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Conformational reorganization viewed by the raman spectrum of aromatic polyesters (1986)

Kim, Jong S. ; Lewin, Menachem ; Bulkin, Bernard J.

Bognor Regis [u.a.] : Wiley-Blackwell

Journal of Polymer Science Part B: Polymer Physics 24 (1986), S. 1783-1789

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Details

ISSN: 0887-6266

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: Analysis is made of the asymmetry of the carbonyl stretching vibration of poly(ethylene terephthalate) and poly(propylene terephthalate) as a function of annealing frrom amorphous to crystalline polymer. An apparently anomalous behavior of carbonyl band half-width as a function of density for PPT is shown to be due to this asymmetry. The results are interpreted in terms of the conformational redistribution which occurs upon annealing.

Additional Material: 5 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/polb.1986.090240813

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