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Free Radicales of TATB (1981)

Britt, A. D. ; Moniz, W. B. ; Chingas, G. C. ; [et al.]

Weinheim : Wiley-Blackwell

Propellants, Explosives, Pyrotechnics 6 (1981), S. 94-95

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ISSN: 0721-3115

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology

Notes: TATB (1,3,5-triamino-2,4,6-trinitrobenzene) forms an unusually stable free radical upon irradiation with ultraviolet light. Extraction with dimethylsulfoxide yields a liquid solution ESR spectrum which is, apparently, due to a TATB-H adduct. The g-values, spectral widths, and hyperfine assignments for the solution radical are given.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/prep.19810060403

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