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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Astrophysics and space science 134 (1987), S. 361-379 
    ISSN: 1572-946X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Mid-infrared extinction coefficients of five natural amorphous silicates and seven synthetic glasses were measured. Three bands at about 10, 12, and 20 μm were seen for all the measured samples. The quantities of these bands are found to have good correlations with the SiO2 content of the samples. The correlations are the most remarkable for the 10 μm band. As the SiO2 content decreases, the peak wavelengthλ m shifts to longer side, the peak heightK m decreases and the full width of half maximumW increases. A quantityλ m K m W is constant within 15%. Empirical formula $$\lambda_m (\mu m) = {11.10-2.30 x 10^-2} {[SiO_2 wt.\%]} \pm 0.15$$ and $$W(\mu m) = {5.14-4.68 x 10^- 2} {[SiO_2 wt.\%]} \pm 0.30$$ are obtained for the measured samples. Therefore, the correlation is present between the 10 μm peak wavelengthλ m and peak widthW for amorphous silicates. The change in peak widthW is remarkable compared the change in peak wavelengthλ m as the SiO2 content varies. For the 12 μm band the correlations with the SiO2 content are not so good. A tendency that theλ m shifts to the red and theK m lowers as the decreasing SiO2 content are found. For the samples with SiO2 content less than 50% the 12 μm band cannot recognized as the peak. For the 20 μm band, theλ m is almost independent on SiO2 content and theK m lowers with decreasing SiO2 content. The results are compared with the observed 10 μm band of the astronomical objects. A method to estimate the SiO2 content of astronomical grain materials is proposed and 48±8% SiO2 wt.% is found corresponding to the peak wavelength of 9.7 μm and the peak width of 2.5–3.0 μm of typical celestial objects.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Astrophysics and space science 134 (1987), S. 95-102 
    ISSN: 1572-946X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The far-infrared extinction spectra of fused silica grains with the size range from 1.8 μm to 60 Å were measured. The spectra depend clearly on the grain size. For large grain sizes (from 1.8 μm to 400 Å) the spectra show almost the λ−2 dependence (λ is the wavelength), which resembles that of the bulk material. For fine grains (70 and 60 Å) the spectra are less steep, the wavelength dependence being λ−1. This grain size dependence of extinction spectra agrees essentially with the prediction of Seki and Yamamoto.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1572-946X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Extinction measurements were made for some silicate and iron-oxide mineral grains in mid- and far-infrared region. For far-infrared region, high temperature magnesium silicates such as olivine and pyroxenes show the absorption spectra of steep dependence as λ−3 (λ being the wavelength) with some peak structure, but the spectrum of magnetite shows λ−1 dependence.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1573-0794
    Keywords: Comet ; infrared ; dust ; silicates ; olivine ; pyroxene
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The NASA Ames HIFOGS spectrometer observed comet C/1995 O1 (Hale-Bopp) at epochs including 96 Oct 7–14 UT (2.8 AU), 97 Feb 14–15 UT (1.2 AU), 97 Apr 11 UT (0.93 AU), and 97 Jun 22, 25 UT (1.7 AU). The HIFOGS 7.5–13.5 μm spectrophotometry (R = 360 - 180) of the silicate feature at 2.8 AU is identical in shape to the ISO SWS spectra of comet Hale-Bopp (Crovisier et al., 1997); the strong 11.2 μm peak in the structured silicate feature is identified as olivine. Upon close passage to the sun, the HIFOGS spectra at 1.2 AU and 0.93 AU reveals strong peaks at 9.3 μm and 10.0 μm. The post-perihelion 10 μm silicate feature at 1.7 AU is weaker but has nearly the same shape as the pre-perihelion spectra at 1.2 AU, reverting to its pre-perihelion shape: there is no change in the dust chemistry by close passage to the sun. The appearance of the strong peaks at 9.3 μm and 10.0 μm at rh ≲ 1.7 AU is attributed to the rise in the contribution of pryoxenes (clino-pyroxene and orthopyroxene crystals) to the shape of the feature, and leads to the hypothesis that the pyroxenes are significantly cooler than the olivines. The pyroxenes are radiating on the Wien side of the blackbody at 2.8 AU and transition to the Rayleigh-Jeans tail of the blackbody upon closer approach to the Sun. Composite fits to the observed 10 μm silicate features using IDPs and laboratory minerals shows that a good empirical fit to the spectra is obtained when the pryoxenes are about 150 K cooler than the olivines. The pyroxenes, because they are cooler and contribute signficantly at perihelion, are more abundant than the olivines. The perihelion temperature of the pyroxenes implies that the pyroxenes are more Mg-rich than the other minerals including the olivines, amorphous olivines, and amorphous pyroxenes. The PUMA-1 flyby measurements of comet P/Halley also indicated an overabundance of Mg-rich pryoxenes compared to olivines. Comet Hale-Bopp's pyroxenes are similar to pyroxere IDPs from the ’Spray‘ class, known for their D-richness and their unaltered morphologies: Hale-Bopp's Mg-rich pyroxenes may be pristine relic ISM grains.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Astrophysics and space science 88 (1982), S. 89-98 
    ISSN: 1572-946X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Extinction coefficients were measured for three kind of hydrous silicate minerals, montmorillonite, chlorite and serpentine, from 7 to 140 μm. The infrared extinction coefficients of these minerals show (1) a few broad bands in the mid-infrared region and (2) a less steep wavelength-dependence in the far-infrared region, in contrast to those of high-temperature magnesium silicates. In the far-infrared region, montmorillonite shows a λ−0.8±0.1 dependence (λ, the wavelength) without any band structure, chlorite has a double maxima structure around 80 μm, and serpentine shows a rather steep dependence with a small peak at 77 μm. The changes of mid-infrared spectra by heating were measured. Change in chlorite spectrum is the most significant. Many fine features appear by heating and then they disappear. Above 900°C one broad feature remains around 10 μm. Fine features of the montmorillonite spectrum disappear by heating. For serpentine, many new peaks appear and the spectrum resembles the spectrum of olivin. In near-infrared a band around 2.72 μm disappears by heating. Extinction coefficients at very low temperatures were measured in the far-infrared region. For montmorillonite and serpentine, the spectrum is the same as that at room temperature. The double peaks of chlorite around 80 μm become higher.
    Type of Medium: Electronic Resource
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