ISSN:
1573-9171
Keywords:
iron acrylate
;
metal-containing monomers and polymers
;
X-ray photoelectron
;
Mössbauer
;
IR, and mass spectra
;
structure
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract A new cluster-type monomer [Fe3O(OCOCH=CH2)6]OH · 3H2O was synthesized by the reaction of acrylic acid with freshly prepared iron hydroxide. The monomer was characterized by various physicochemical methods. It has been shown that the acid residues are bound to the metal atoms through carboxyl groups in a bridge-like or bidentate fashion, and the double bond does not participate in the coordination. The mechanism of thermal fragmentation of the [Fe3O(OCOCH=CH2)6]+ cluster was studied. It was demonstrated that the radical polymerization of this monomer involved bidentate acrylate groups. No reduction of Fe3+ during the polymerization was observed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00697035
Permalink