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Digitale Medien

Asymmetric activation of chiral BINOL-zirconium catalysts: Effect of a product-like activator (1998)

Volk, Thorsten ; Korenaga, Toshinobu ; Matsukawa, Satoru ; [weitere]

New York, NY [u.a.] : Wiley-Blackwell

Chirality 10 (1998), S. 717-721

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Details

ISSN: 0899-0042

Schlagwort(e): zirconium ; binaphthol (BINOL) ; allylation ; asymmetric activation ; enantioselective carbon-carbon bond formation ; chiral high-performance liquid chromatography ; induction period ; product-like activator ; Chemistry ; Organic Chemistry

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: The asymmetric activation of binaphthol (BINOL)-zirconium catalysts is described on the enantioselective allylation of benzaldehyde with allyltin reagents. This model reaction has been used with the intention of establishing a protocol for a zirconium-based catalyst system, to be followed by structural studies. Initial results are reported that characterise a number of interesting features, namely the influence of an induction period and a high level of asymmetric activation obtained after addition of a product-like activator. Chirality 10:717-721, 1998. © 1998 Wiley-Liss, Inc.

Zusätzliches Material: 3 Ill.

Materialart: Digitale Medien

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