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Über Diels-Alder-Reaktionen des C60-Fullerens Vorläufige Mitteilung (1993)

Krätler, Bernhard ; Puchberger, Michael

New York, NY : Wiley-Blackwell

Helvetica Chimica Acta 76 (1993), S. 1626-1631

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ISSN: 0018-019X

Keywords: Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: On Diels-Alder Reactions of the C60-FullereneWe report on the regioselective [4+2] cycloaddition of Buckminsterfullerene C60(1) at room temperature with 2,3-dimethylbuta-1,3-diene and with the monoterpene 7-methyl-3-methylideneocta-1,6-diene (= myrcene) and on the spectroscopic characterization of the corresponding crystalling monoadducts 2 and 3. According to these experiments, 1 acts as a reactive dienophile, which can be functionalized regioselectively under mild and controlled conditons.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/hlca.19930760419

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