ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
Trichlorooxo[1,3-propanediylbis(diphenylphosphine)-P,P′]rhenium(V), [ReCl3O(C27H26P2)], crystallizes with four formula units per unit cell. The crystal structure consists of neutral complexes of [ReOCl3(dppp)] [dppp is 1,3-bis(diphenylphosphino)propane] packed by H...π-ring interactions. The Re atom is octahedrally coordinated to the oxo anion, three Cl atoms and two P atoms from the dppp ligand. The six-membered ring formed by the bidentate dppp ligand and the rhenium metal centre is in a chair conformation. The title compound is an intermediate in the synthesis of bis(dppp) complexes of rhenium.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270100006983
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