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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 89 (2001), S. 3301-3306 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Thin aluminum oxide barrier layers have been studied by in situ x-ray photoelectron spectroscopy to determine their oxidation degree dependence on oxidation time and method (thermal or plasma oxidation). A 1.5 nm thick Al layer is found to completely oxidize by exposure to an oxygen plasma for a time in the interval 30–60 s, i.e., using the conventional plasma oxidation method. For times less than 30 s, however, we observed not only a metallic-Al peak but the formed oxide was substoichiometric. The composition of the formed oxide increased towards Al2O3 as the oxidation continued. It was also found possible to oxidize up to 1 nm of Al, at room temperature, upon deposition on Co previously exposed to 9.3 Pa (70 mTorr) oxygen for 10 s. Annealing junctions with the idealized structure Co/Al2O3/Co at up to 275 °C was found to increase their magnetoresistance (up to 35%) and resistance (up to a decade), if the Al was deposited on an oxidized Co bottom electrode. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 89 (2001), S. 1965-1972 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: This article presents results of a study initiated to characterize the plasma-oxidation process of very thin Al films, a technology commonly used to produce good barrier layers for magnetic spin-tunnel junctions. The behavior of oxygen in the oxidizing Al layer is determined using both quantitative (Rutherford backscattering spectrometry, transmission electron microscopy) and qualitative (x-ray photoelectron spectroscopy (XPS), secondary ion mass spectrometry) analytical techniques. We have applied in situ XPS and experimented with 18O2 to unravel details of the oxidation mechanism. In addition, the influence of the oxygen pressure on the oxidation rate was established, both with and without a plasma being present. From optical emission spectra it is concluded that this pressure has a minor effect on the relative abundance of excited species in the oxygen plasma. When combined, these data constitute the basis of a model that distinguishes several steps in the plasma oxidation of Al. At the start, oxygen penetrates rapidly throughout the total Al layer, followed by a period of increasing oxygen concentration but constant oxide thickness. Finally, the Co underlayer becomes involved in the oxidation process, which marks the deterioration of the spin-tunnel junction. Evidence is obtained that for the thicker initial Al layers the Co electrode layer starts to oxidize before completion of the Al oxidation. This explains why for 0.8-nm-thick Al films the highest tunnel-magnetoresistance effect is obtained for stoichiometric Al2O3, whereas for 1.5 nm Al this occurs while the oxide is still substoichiometric. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 88 (2000), S. 5894-5898 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: An enhancement of the giant magnetoresistance effect is investigated in spin valves where oxide layers, which are formed from magnetic layers, are incorporated in the structure. Information about Co–Fe based nanooxide layer (NOL) is obtained via x-ray photoelectron spectroscopy and Rutherford backscattering spectrometry. Cross-section transmission electron microscopy is also used to explore the effect of an NOL on the polycrystalline structure of the spin valve. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 85 (1999), S. 5531-5533 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A new, robust giant magnetoresistance (GMR) material system is described that comprises an exchange-biased artificial antiferromagnet. For the exchange biasing Ir18Mn82 is used because of its high blocking temperature. Experiments have demonstrated that this material can withstand magnetic fields larger than 150 kA/m and annealing at temperatures above 275 °C without irreversible damage. At higher temperatures the GMR effect starts to decrease due to atomic diffusion; the exchange-biasing effect, however, does not disappear, which means that this is no longer the limiting factor. The excellent magnetic and thermal robustness, combined with the unambiguous asymmetric magnetoresistance curve, makes this GMR material system very suitable for application in (e.g., automotive) sensors. © 1999 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 89 (2001), S. 6922-6924 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The enhancement of the magnetoresistance effect, induced by incorporating nano-oxide layers (NOLs) in a bottom-type spin valve, was studied for various preparation conditions. The effect of a NOL in the Co90Fe10 pinned layer was found to depend critically on the oxygen pressure applied to form the thin oxide film. Pressures over 10−3 Torr O2 yield oxides thicker than about 0.7 nm, which apparently deteriorate the biasing field which exists over the oxide. The magnetoresistance values can further be raised by forming a specular reflecting oxide on top of the sense layer. Promising results were obtained with an Al2O3 capping layer formed in a solid-state oxidation reaction that occurs spontaneously when a thin Al layer is deposited on the oxidized surface of the Co90Fe10 sense layer. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 56 (1990), S. 2530-2532 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Hydrogen transport in low-pressure chemical vapor deposited Si3N4 has been investigated using samples consisting of a double layer of hydrogenated and deuterated nitride films. Concentration depth profiles of hydrogen and deuterium were measured using elastic recoil detection. Diffusion coefficients for D were derived from the deuterium concentration depth profiles before and after annealing at temperatures in the range 700–1000 °C. The diffusion coefficient is characterized by an activation energy of 2.94 eV for the entire temperature range. Its value varies between 10−17 cm2/s at 700 °C and 5×10−14 cm2/s at 1000 °C.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 53 (1988), S. 2149-2151 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Hydrogen in low-pressure chemical vapor deposited oxynitride films was measured using elastic recoil detection with 2 MeV He ions. A distinction between N- and Si-bonded hydrogen could be made for films deposited from ND3 instead of NH3. The analyses reveal that on an average three times as much hydrogen is incorporated as NH relative to SiH, and that a maximum in this ratio is present in oxynitride with a composition around O/N=0.3. This optimum coincides with a maximum in total hydrogen content in the film of 3.2 at. %. Hydrogen desorption occurs in a narrow temperature interval around 950 °C and proceeds virtually in an identical way for both binding types.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 88 (2000), S. 429-434 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: In this paper we present results on how the plasma oxidation of a thin (1.5 nm) Al layer proceeds. Transmission electron microscopy of a Co/Al–oxide multilayer was used to determine the thickness of the oxides and Rutherford backscattering spectrometry and elastic recoil detection were utilized in order to determine the oxygen content. The oxide was also characterized via ac impedance measurements. These measurements indicated that the oxidation of Al on Co occurs in three discrete steps. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 87 (2000), S. 6665-6667 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The temperature dependence of the giant magnetoresistance (GMR) ratio, resistance and exchange-biasing field for a spin valve comprising an Ir19Mn81-biased artificial antiferromagnet (AAF) has been studied up to 325 °C. Up to 200–250 °C the temperature effects are reversible, at higher temperatures gradual irreversible changes are observed, probably due to atomic diffusion. The magnetoresistance effect is even at 200 °C still higher than for anisotropic magnetoresistance sensors at room temperature. The resistance of the multilayer shows a maximum around 250 °C. We found that this is due to the peculiar behavior of Ir–Mn, which has a negative temperature coefficient of the resistance. This provides a possibility to tune the temperature coefficient for the complete multilayer by varying the thickness of the Ir–Mn layer. The relative decrease of the exchange-biasing field as a function of temperature is much smaller for spin valves with AAF than for conventional spin valves (without AAF). Furthermore, it was demonstrated that the GMR ratio can be increased to 12% at room temperature by using a dual spin valve with two AAFs. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The incorporation of nitrogen and hydrogen during nitridation of SiO2 was studied over the temperature range of 800–1000 °C and for ammonia pressures of 1, 5, and 10 atm. The nitrogen content of the nitrided films was determined with Rutherford-backscattering spectrometry and elastic-recoil detection. Nitrogen in-depth profiles were obtained applying Auger analysis combined with ion sputtering. Hydrogen profiles in the films were measured using nuclear-reaction analysis. Both the nitrogen and hydrogen incorporation were found to increase with temperature in this range. A higher ammonia pressure primarily increases nitridation of the bulk of the oxide films. Depending on the nitridation conditions, up to 10 at.% of hydrogen may be incorporated. As distinct from the nitrogen profiles, the hydrogen in-depth profiles are essentially flat. The concentration of hydrogen in the films, however, was always found to be smaller than that of nitrogen: measured H/N ratios varied between 0.25 and 0.85, the smaller values being obtained for the thinner oxides and higher nitridation temperatures. The model previously postulated to explain the nitrogen incorporation during atmospheric nitridation of SiO2 proves to be valid at higher pressures as well. By considering the role of OH as a reaction product of the nitridation process, the hydrogen results can be accommodated within the same concept. The model predicts a low H/N-incorporation ratio for a thin surface and interface layer and a substantially larger ratio for the bulk of the film. If this prediction is correct, which seems to be indicated by the etch-rate behavior of the nitrided oxides, then this would have considerable importance for the electrical properties of this material.
    Type of Medium: Electronic Resource
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