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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Macromolecules 23 (1990), S. 4135-4140 
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 25 (1987), S. 2021-2024 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 25 (1987), S. 1781-1791 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A novel diisocyanate monomer, thiophene-2,5-diisocyanate (ThDI) was prepared from readily available adipic acid via the intermediate formation of thiophene-2,5-dicarboxylic acid chloride (ThDAC) and thiophene-2,5-dicarboxylic acid azide (ThDAA) which was subjected to a Curtius rearrangement. Polyurethanes and polyureas containing 2,5-thiophenylene linkage were synthesized by the polycondensation of thiophene-2,5-diisocyanate with various diols and diamines, respectively, in N,N-dimethylformamide. Polymerization conditions were optimized and the high yields of polymers were obtained. The identity of ThDI, model compounds, and the resulting polymers was confirmed by elemental analysis and spectroscopic methods. These polyurethanes and polyureas were found to have inherent viscosities in the range of 0.33-0.68 dL/g. Some physical properties of these polymers were also investigated.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 36 (1998), S. 949-953 
    ISSN: 0887-624X
    Keywords: conjugated polyacetylene ; acetylene derivative ; poly(HPB) ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The new conjugated polyacetylene derivative dehydrated poly(4-hydroxy-4-phenyl-1-butyne) [dehydrated poly(HPB)] was synthesized from poly(4-hydroxy-4-phenyl-1-butyne) [poly(HPB)], which was obtained by the polymerization of 4-hydroxy-4-phenyl-1-butyne. The resulting dehydrated poly(HPB) was soluble in common organic solvents. The dehydrated poly(HPB) was found to have extended conjugated polyene structure. The dehydrated poly(HPB) was thermally stable up to 300°C. The electrical conductivity of I2-doped dehydrated poly(HPB) was 10-2 S cm-1. © 1998 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 36: 949-953, 1998
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 33 (1995), S. 2135-2140 
    ISSN: 0887-624X
    Keywords: MoCl5-based catalysts ; spiro structure ; cyclopolymerization ; nonconjugated dienes ; poly(CPDK) ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The Polymerization was carried out by MoCl5 and WCl6 associated with various organo-metallic cocatalysts. MoCl5-based catalysts were found to be more effective. Polymerization of monomer containing a spiro structure proceeded rapidly to reach 80% yield within 2 h at 30°C. Polymerization of monomer led to a soluble, purple colored polymer with number average molecular weight (Mn) of 50000. Elemental analysis, 1H-NMR, 13C-NMR, IR, and UV-visible spectra of the resulting polymer indicated that the polymer contains alternating double and single bonds along the polymer backbone and a cyclic recurring unit with a double spiro structure. In addition, the polymer had good oxidative and thermal stability and good solubility in common organic solvents. © 1995 John wiley & Sons, Inc.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 30 (1992), S. 2143-2148 
    ISSN: 0887-624X
    Keywords: group transfer polymerization ; amphiphilic block copolymer ; surface activity in water ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Different poly(tert-butyl methacrylate) (PTBMA)-poly(alkyl methacrylate) (PAMA, alkyl=CH3, n-C4H9) triblock copolymers were synthesized by group transfer polymerization. They were obtained by first preparing “living” PAMA using a difunctional initiator, followed by polymerization of TBMA in THF at room temperature, in the presence of a nucleophilic catalyst. The segment molecular weights and compositions of TBMA segment could be controlled by regulating the feed ratio of two monomers and the ratio of monomer to initiator. As supported by 1H-NMR, IR analysis, and titration, the PTBMA blocks could be quantitatively hydrolyzed into poly(methacrylic acid) (PMAA) blocks whereas the PAMA blocks were not hydrolyzed. The water-soluble amphiphiles prepared by neutralization of the PMAA block displayed surface-active behavior in water, which was characterized by a critical micelle concentration. The thermogravimetric analysis demonstrated the loss of tert-butyl groups. © 1992 John Wiley & Sons, Inc.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Polymers for Advanced Technologies 7 (1996), S. 483-492 
    ISSN: 1042-7147
    Keywords: compatibilizer ; polymer blends ; recycling ; waste plastic mixtures ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In this work, comparative studies have been made to investigate the effectiveness of several compatibilizers for three kinds of virgin plastic mixtures, high-density polyethylene (HDPE)/polypropylene (PP), low-density polyethylene (LDPE)/PP and HDPE/polystyrene (PS) blends, in order to gain insight into the recycling of wastes from those frequently encountered mixed plastics. Three copolymers were tested as potential compatibilizers for those blends: ethylene - propylene - diene terpolymer (EPDM)-g-maleic anhydride (EPDM-g-MAH) for HDPE/PP and LDPE/PP blends, styrene - ethylene (butylene - styrene) (SEBS) and SEBS-g-MAH, for HDPE/PS blends. The properties and morphology of each ternary blend containing a coplymeric compatibilizer were measured with differential scanning calorimeter, X-ray diffractometer, tensile tester and scanning electron microscope. The concentration of the graft copolymer was varied from 0 to 20 phr, whereas the blend composition was fixed at 50/50 by weight %. It was found that EPDM-g-MAH showed good compatibilizing effect for LDPE/PP blends but not for HDPE/PP blends, in general. It was also found that SEBS showed much better compatibilizing effects for HDPE/PP blend than the SEBS-g-MAH blend.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Difference ABA triblock copolymers (1) of 2-trimethylsilyloxyethyl methacrylate (TMS-HEMA) and n-butyl methacrylate (BMA) were prepared by group transfer polymerization (GTP) with a difunctional initiator. The polydispersities of the block copolymers were in 1.16 to 1.43 range. From selective and quantitative hydrolysis of poly (TMS-HEMA) segments of 1, block copolymers (2) of 2-hydroxyethyl methacrylate (HEMA) and BMA could be prepared. 2 showed different solubilities depanding on their compositions. From transmission electron micrographs of films casted from dilute solution of the polymers, it was found that microphase separation of the hydrophilic and hydrophobic domains occurs in different geometries.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 194 (1993), S. 251-257 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Living cationic polymerization of styrene in the presence of 1-chloroethylbenzene (1-CEB)/SnCl4 as an initiating system has been investigated in chloroform at -15 to +20°C. The best results were obtained at -15°C. Under these conditions, the number-average molecular weight (M̄n) of the products increases linearly with increasing monomer conversion. The molecular weight of the polymer produced could be further increased by adding additional monomer. The molecular weights are in good agreement with the calculated values assuming that one living polymer chain is formed per one 1-CEB molecular. The molecular weight distributions of the polymers obtained are narrow (ratio of weight- to number-average molecular weights 1,07 ≤ M̄w/M̄n ≤ 1,17). The living character of these polymerizations depends on the polarity of the solvent and on temperature.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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