ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Synthesis of Aryl-bis(trimethylsilyl)-phosphonic Acid Esters via Tris-trimethylsilylphosphite - a Contribution of the Nickel-catalyzed Michaelis-Arbusov Reaction.The preparation of various aryl-bis(trimethylsilyl)-phosphonic acid esters via P(OSiMe3)3 or a mixture of HP(O)(OSiMe3)2/P(OSiMe3)3/Me3Si—NH—SiMe3 in presence of nickel compounds are described. The structures are proved by the 31P n.m.r. spectra.
Notes:
Es wird die nickel-katalysierte Darstellung verschieden-substituierter Aryl-bis(trimethylsilyl)-phosphonsäureester via Tris-trimethylsilylphosphit bzw. eines Gemisches von Bis-/Tris-trimethylsilylphosphit/Hexamethyldisilazan beschrieben. Ihre 31P-NMR-Daten werden mitgeteilt.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19855291020
Permalink