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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 64 (1960), S. 196-198 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 64 (1960), S. 1338-1339 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. S24 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. 422-424 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A method is described for measuring the rigidity of a curing polymer system throughout its complete course of reaction (liquid to solid). In this technique, a braided fiber (nylon), impregnated with the polymer system to be studied, is used as the supporting member for a free, torsionally vibrating mass. From the frequency of the vibration, the apparent rigidity modulus Ḡ of the impregnated braid is calculated. The rigidity of the reacting polymer is thus followed nondestructively during the curing period. In a further development, the term relative rigidity Ḡ/Ḡ0 is introduced to normalize the rigidity parameter to a more experimentally adaptable quantity. The curing behavior of several types of polymer is presented to illustrate the general utility of the method.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 19 (1979), S. 662-663 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 177-179 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Equipment is described for measurement of Young's and shear modulus on the same identical polymer sample, by a free-vibration method. Strain gauges are used as sensors in an automatic recorder. Young's modulus and damping, shear modulus and damping and Poisson's ratio are reported over a range of temperature for polypropylene, Nylon 66 and poly (methylmethacrylate). It is found that Poisson's ratio shows a dip in the glass transition region and that values greater than the infinitesimal strain limit of 0.5 are obtained in the rubbery region.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 3 (1963), S. 201-209 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The application of a free vibration technique to the study of the cross-linking of an epoxy resin by an amine is demonstrated. Curing curves are presented showing the changes in dynamic mechanical flexural modulus and damping during reaction. At room temperature, the glass transition point is reached after a conversion of about 65% of the epoxide groups. Comparisons of the dynamic mechanical and infrared curing curves indicate a lowering of the reaction rate after this point is reached. Finally, an activation energy for the epoxy-amine cross-linking reaction is calculated.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 19 (1979), S. 687-691 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Time/temperature cure profile diagrams of a nylon-epoxy adhesive and a rubber-modified epoxy based structural adhesive have been established from isothermal-cure time torsional braid analysis measurements. The characteristic zones of liquid, gel-rubber and glassy state behavior are noted on the diagrams. With the nylon-epoxy adhesive, the time/temperature cure profile is ill-defined since all the TBA data had to be obtained (due to the particular curing agent involved) at isothermal conditions above the glass temperature of the finally cured adhesive. In comparison, the rubber-modified epoxy system showed distinct zones reflecting the various rheological states traversed during the thermosetting process. The dynamic mechanical. (Rheovibron), morphology, and adhesive joint strength properties are examined as a function of cure cycle.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. S35 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 7 (1963), S. 685-694 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An analysis of the parameters involved in torsional braid measurements is given. It is found that the amount of polymer on the braid controls the level of rigidity modulus attained by the composite specimen, but does not affect the measured glass transition temperature of the polymer. Treating the torsional braid system as a fabric braid filled polymer system, an empirical relation is given relating the measured modulus, G, to the modulus of the unfilled polymer, G0, and the volume fractions of voids, ϕv and support ϕs. This equation takes the form, \documentclass{article}\pagestyle{empty}\begin{document}$$ G/G_0 {\rm } = {\rm [1 } + {\rm (}k_s \phi _s {\rm } + {\rm }k_v \phi _v )]/[1 - (S_s ^\prime \phi _s + S_v ^\prime \phi _v )]^2 $$\end{document} where ks, kv, Ss′, and Sv′ are constants. This equation is evaluated for the polystyrene-cotton thread system. The effect of braid length on the measured modulus is discussed.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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