ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The title compound, (η5-cyclopentadienyl)[(1,2,3,4,5-η)-4-ferrocenyl-1,2,5,6-tetrakis(trimethylsilyl)cyclohexa-2,4-dien-1-yl]titanium(II), [TiFe(C5H5)2(C23H42Si4)] or [Ti{η5-C6H2{Fe(η5-C5H4)(η5-C5H5)}{Si(CH3)3}4}(η5-C5H5)], possesses two directly linked metallocene units that subtend an angle of 52.9 (1)° (defined by the least-squares planes of the directly connected π-ligands) associated with the steric requirements of the bulky trimethylsilyl substituents. The cyclohexadienyl ligand adopts an envelope conformation; the perpendicular distance of its η5-plane to the Ti atom is 1.512 (1) Å.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270100010167
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