ISSN:
0887-624X
Keywords:
high-temperature poly (ether sulphone)
;
amine-ended polymer
;
maleimide-ended polymer
;
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
New high-temperature amorphous polymers with chlorine, amine, and maleimide chain-ends have been synthesized by nucleophilic polycondensation and fully characterized by 13C-NMR, 1H-NMR, and potentiometric titration. From chain-end determination, number average molecular masses were calculated. It was confirmed that transetherification during the synthesis led to a randomized polymer of the monomer residues. For nominally amine-ended polymers obtained by addition of m-aminophenol at the end of the synthesis, a small amount of hydroxyl chain-ends was observed. This is ascribed also to transetherification. Complete reaction of the amine chain-ends with maleic anhydride was demonstrated. Reaction of hydroxyl chain-ends with acetic anhydride was also observed. The thermal stability of these different polymers was investigated; lower thermal stability was observed for amine and maleimide-ended polymers. By two different methods, a Tg around 270d°C was determined for these novel amorphous aromatic polymers. © 1994 John Wiley & Sons, Inc.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pola.1994.080321618
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