Electronic Resource
New York, NY
:
Wiley-Blackwell
International Journal of Quantum Chemistry
39 (1991), S. 47-57
ISSN:
0020-7608
Keywords:
Computational Chemistry and Molecular Modeling
;
Atomic, Molecular and Optical Physics
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A set of electron impact cross sections for vibrational excitation of water in the gaseous phase are first presented. The associated loss function is used in conjunction with a rotational loss function to generate efficiencies for the conversion of low-energy electron energy to rotational and vibrational excitation. An analogous calculation is carried out for intramolecular and intermolecular modes in the liquid phase leading to similar results. We also examine a simple model for the time dependence of the electron hydration process based on a square well with a time-dependent radius and well depth. We can fit the time and wavelength dependence of the experimental absorption coefficients if we introduce another time-dependent parameter that might be encompassed by a diffuse potential well model.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/qua.560390107
Permalink
| Library |
Location |
Call Number |
Volume/Issue/Year |
Availability |
