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  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Ground water monitoring & remediation 17 (1997), S. 0 
    ISSN: 1745-6592
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: An algorithm is presented that allows estimation of the saturation and composition of a single of multi-component NAPL within a core sample. These estimates are possible because, in addition to distributing the organic chemicals between aqueous, sorbed, air, and NAPL phases according to traditionalpartitioning equations, the algorithm incorporates equations for the conservation of mass and volume. A unique solution is obtained by solvihg the set of nonlinear equations implicitly. The algorithm is built into a code called NAPLANAL, which is tested and applied to actual core samples collected in the field.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Ground water monitoring & remediation 23 (2003), S. 0 
    ISSN: 1745-6592
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: An automated in-line analytical system has been developed to provide near real-time results for partitioning interwell tracer testing (PITT) and surfactant enhanced aquifer remediation (SEAR). The analytical methodology is based on gas chromatography (GC) with flame ionization detection and direct aqueous injection. The system was constructed from both commercially available and custom-manufactured components that are linked electronically to facilitate autonomous operation. For the field trials presented herein, the in-line GC method provided superior or comparable PITT and SEAR data compared to conventional sample collection followed by shipment and analysis at a commercial analytical laboratory. Analytical precolumns were shown to effectively safeguard the integrity of the analytical column, despite the consecutive analysis of more than 1000 samples per PITT or SEAR. Additionally, the use of the in-line GC resulted in an 85% and 74% reduction in analytical costs per PITT and SEAR, respectively.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1745-6592
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: A demonstration of surfactant-enhanced aquifer remediation (SEAR) was conducted at Hill Air Force Base (AFB), Utah. Two surfactant floods were undertaken in a test section of a heterogeneous alluvial aquifer with a hydraulic conductivity range of 2.8 to 8.6 ft/day (10-5 to 10-4 m/sec) and a pore volume of approximately 15,000 gallons (57 m3). The wellfield installed for the demonstration consisted of lines of three injection and three extraction wells, a central monitoring well, and a single hydraulic control well. No physical barriers to flow, such as sheet-pile walls, were employed; surfactant flooding was controlled entirely by hydraulic manipulation of the flow field. The inter-well distance between injectors and extractors was 20 feet (6 m); the distance between individual injectors and extractors in line was 10 feet (3 m). The water table was 25 feet (7.6 m) below ground surface with a saturated zone approximately 19-feet thick (5.8 m). Residual dense nonaqueous phase liquids (DNAPL) remained in a zone of alluvium 42 to 46 feet (13 to 14 m) below ground surface following extraction of free-phase DNAPL. The injectors and extractors were screened in this DNAPL zone. Three partitioning interwell tracer tests (PITTs) and two surfactant floods were conducted over four months during 1996. The surfactant floods removed 341 out of 346 gallons of residual DNAPL (1290 of 1310 L), according to the PITTs. This represents a total recovery of about 98.5% of the DNAPL volume present in the zone of residual DNAPL as determined by comparing the initial and final PITTs. There was no reduction in hydraulic conductivity due to colloid mobilization during the surfactant floods; in fact, the hydraulic gradient across the test zone decreased as the floods progressed. Concentrations of dissolved total chlorinated hydrocarbons in the test section decreased from 1000 mg/L before the floods to less than 10 mg/L following the floods. This demonstration is evidence of the technical practicability of DNAPL removal from alluvium.
    Type of Medium: Electronic Resource
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