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Dichlorobis(1,2-phenylenediamine)nickel(II) (2000)

Maxcy, Karen R. ; Smith, Randy ; Willett, Roger D. ; [et al.]

Oxford [u.a.] : International Union of Crystallography (IUCr)

Acta crystallographica 56 (2000), S. e454-e454

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ISSN: 1600-5759

Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001

Topics: Chemistry and Pharmacology , Geosciences , Physics

Notes: The title compound, [NiCl2(C6H8N2)2], contains centrosymmetric molecules with two phenylenediamine ligands coordinated in a bidentate fashion. The Ni—N distances are 2.088 (1) and 2.096 (1) Å, and the Ni—Cl distance of 2.4635 (4) Å. The plane of each phenylenediamine molecule makes a dihedral angle of 26.53 (7)° with the NiN4 plane. Extensive hydrogen bonding leads to distinct cleavage in the bc plane.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1107/S0108270100012476

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