ISSN:
1573-9171
Keywords:
3-phenoxy- and 3-phenylthio-1-propynyl substituted derivatives of silicon and germanium
;
synthesis
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Reactions of bromomagnesiopropargyl phenyl ethers and their isostmctural sulfides BrMgC≡CCH2XPh (X = O, S) with MeVinSiCl2, Me(CH2Cl)SiCl2, EtSiHCl2, and Me2SiHCl afforded the corresponding 3-phenoxy- and 3-phenylthio-1-propynyl substituted derivatives of silicon (PhXCH2C≡C)2SiRR1 and PhXCH2C≡CSiHMe2 (X = O, S). Reactions of the above-mentioned Iotsitch reagents with GeCl4 led to the corresponding germanium derivatives (PhXCH2C≡C)4Ge (X = O, S).
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01169729
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