ISSN:
0009-2940
Keywords:
Platinum complexes, five-coordinate
;
Nitrosyl complexes
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The title complex has been prepared in 36% yield by reaction of [NBu4]2[trans-Pt(C6Cl5)2Cl2] with NOClO4 (1:1) in CH2Cl2. The anion exhibits an almost tetragonal-pyramidal geometry (X-ray analysis), the platinum atom being virtually located in the basal plane and the NO ligand occupying the apical position. The Pt—N—O unit is bent [119.5(8)°].
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19941270412
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