ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A general expression is derived for the approach to a new equilibrium when a monomer/dimer solution is diluted by a factor of n. The error introduced by a simple exponential treatment is analyzed. The response of a trityl monomer/dimer equilibrium to dilution by a factor of two in a stopped-flow apparatus has been used to measure the rate constant k11. The results fall on the same Eyring plot with those obtained at lower temperatures, by another method, in the early 1930's by Ziegler and co-workers. © John Wiley & Sons, Inc.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550241007
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