Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
94 (1991), S. 1868-1874
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The cross sections for dissociative attachment in the chlorosilanes and chloromethanes for electrons in the energy range 0.2–5.0 eV have been measured. In addition, measurements of the total electron scattering cross sections of the chloromethanes in the 0.2–12.0 eV range are reported. It is observed that dissociative attachment is much more probable in the chloromethanes than the chlorosilanes. This is explained by quantum mechanical calculations which reveal qualitative differences in the nature of the electron–molecule complex for the silanes as compared to the methanes.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.459960
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