ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
Small-angle neutron scattering measurements are reported for solutions of cryptand 222 and cryptates K+222, ClO4− and Ba2+222, 2ClO4− in deuterated acetonitrile at 25 °C. Solute–solute correlation functions are inferred from the experimental scattering spectra by means of hypernetted chain (HNC) calculations with semiempirical solvent-averaged potentials. Due to their specific structure, cryptands and their complexes are convenient models for uncharged and weakly charged Brownian particles.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.463773
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