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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 91 (1969), S. 5659-5660 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 54 (1989), S. 1057-1059 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Single-crystal x-ray diffraction data from DyBa2Cu4O8 are used to confirm the structure of RBa2Cu4O8 (R=Y, Nd, Sm, Eu, Gd, Dy, Ho, Er, and Tm), all of which have been synthesized in bulk and display substantial Meissner diamagnetism. The structure is orthorhombic, space group Ammm, with a=3.846 3(3), b=3.872 6(3), and c=27.237(2) A(ring). Copper-oxygen layers parallel to (001) are dimpled as in the 1-2-3 structure. Unique copper-oxygen strips parallel to (100) have copper in distorted square-planar coordination. Magnitudes of oxygen anisotropic thermal vibrations are significantly less than in the 1-2-3 structure; thus the oxygen content of 1-2-4 is expected to be significantly more stable.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: We have developed and tested an inexpensive ion detector with dark-count rates below 10−4 s−1 and excellent background rejection. Each 40-keV ion that strikes a grazing-incidence Al2O3 conversion dynode ejects a few tens of secondary electrons, which enter separate pores of a microchannel plate and are independently multiplied to saturated pulse height. The pulses are summed to produce an output signal that is proportional to the number of secondary electrons. This permits pulse-height discrimination against backgrounds of low-energy ions, electrons, and photons. We have successfully tested the detector with C+, Na+, K+, Rb+, and Cs+ at 5–40 keV, and with 36-keV C− and CH−. It should detect ions and neutrals of all species, at energies above 5–10 keV, with good efficiency and excellent background discrimination. Counting efficiency and background discrimination improve with higher ion energy. The detector can be operated at pressures up to at least 2×10−7 Torr and be exposed to air repeatedly without requiring reactivation. The maximum ion count rate is 3×106 s−1 in pulse-counting mode and 6×109 s−1 in current-integrating mode. Detection of 40-keV ions at rates below 10−2 s−1 was required in development of a 10-cm radius 40-keV cyclotron dedicated to high-sensitivity radioisotope dating by accelerator mass spectrometry (AMS). In the cyclotron, the detector suppresses to 6×10−4 s−1 the background count rate from the presence of low-energy ions, photons, and electrons.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 10 (1972), S. 169-178 
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The synthesis and polymerization of several silphenylene siloxane polymer precursors containing a perfluoroalkylsegment in the backbone was carried out. The molecular weight characteristics of polymers from 1,3-bis[p(-hydroxydimethylsilyl)phenyl]hexafluoropropane and 1,3-bis[p(-dimethylaminodimethylsilyl)phenyl]hexafluoropropane were studied as a function of polymerization conditions. Polymers containing the dodecafluorohexane chain segment were also prepared. Polymers having inherent viscosities of 0.55 to 0.9 were obtained. The polymers crosslinked at room temperature to thermoset elastomers which were characterized by improved thermal and oxidative stability over dimethylsilicones. Room temperature swelling of the experimental polymers hydrocarbon solvents was also much lower than that of dimethylsilicones. The polymers containing the (CF2)3 and (CF2)6 linkages had glass transition points of -12°C and -34°C, respectively.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
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