ISSN:
0360-6376
Keywords:
Physics
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The cationic polymerization of N-tert-butyl aziridine (TBA) can be conducted in such a way that the rate of termination is much slower than the rate of propagation, thus permitting preparation of a corresponding polymer which is “temporarily living”. Reactions of N-methyl-N-tert-butyl aziridinium triflate (which is the model for the active species of the living polymer) with different nucleophiles show that, at room temperature, the aziridinium ring reacts almost instantaneously with nucleophiles to form the corresponding ring-opened product. Analogous reactions with the aziridinium end group of living poly-TBA lead to polymers with varying end groups such as hydroxy, ester, primary, secondary or tertiary amino, halogen, and others. End group analysis by means of 360-MHz 1H-NMR nuclear magnetic resonance spectroscopy showed that the concentration of the end groups was in all cases equal to the concentration of the methyl head group, originating form the initiation reaction, if the terminating nucleophile was added five minutes after initiation (at 15°C). Under these conditions the polymerization is quantitative for initiator concentrations down to 0.01 mol L-1.
Additional Material:
8 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pol.1981.170190811
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