ISSN:
0749-1581
Keywords:
NMR
;
1H NMR
;
13C NMR
;
NOE
;
2D-HSC
;
benzoxazinones
;
benzoxazepinones
;
configuration
;
conformation
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
From cis-2-(p-methylbenzoyl)cyclohexanecarboxylic acid (1), diendo-3-(p-methylbenzoyl)bicyclo[2.2.1]heptane-2-carboxylic acid (2) or 2-(p-methylbenzoyl)benzoic acid (3) with stereoisomeric 1,3- or 1,4-amino alcohols with cyclohexane/ene or norbornane/ene skeletons, various partially or fully saturated isoindolo[1,2-b] [1,3]- and -[2,1-a] [3,1]benzoxazinones methylene-bridged derivatives and [1,2-c] [2,4]benzoxazepinones were prepared. For these compounds, containing two hetero rings and two or three cycloalkane rings, the stereostructures (the annelation of the terminal rings and aryl group) were established by 1H and 13C NMR spectroscopy, including DNOE, DEPT and 2D-HSC measurements.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1260330503
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