ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary 1. The reaction of ethyl bromide with silicon in presence of reduced copper was studied in the temperature range 260–380°. 2. The main reaction product was tribromoethylsilane, the yield of which increased considerably with rise in reaction temperature. As a result of the partial pyrolysis of ethyl bromide at the temperature of the formation of bromoethylsilanes, the formation of dibromodiethylsilane, and particularly of bromotriethylsilane, occurred to a much lower extent. The reaction products included also silicon compounds containing silicon-attached hydrogen, namely tribromo- and dibromoethyl-silanes.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00911341
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