ISSN:
0025-116X
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
14CH3O3H was used to quench ethylene polymerization by transition metal catalysts. 3H labeling occurred exclusively for Ti-containing catalysts, whereas more than 95% of the chains were labeled with 14CH3 for the Cr-containing catalysts. Both modes of labeling occurred with V-containing catalysts. The observed phenomena indicate a change of “coordinate-carbanionic” to “coordinate-carbocationic” character for the alkyls of Ti, V and Cr in this order.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/macp.1993.021940611
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