ISSN:
0030-4921
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The vicinal 3Jaa and 3Jee spin-spin coupling constants of a number of deuterated trans-1,2-disubstituted cyclohexenes and the ΔH and ΔS values of the conformational equilibria of these compounds have been determined by computer optimisation of the 3J(HH) = f(T) function. Compounds with - CF3 and CCl3 substituents were shown to have an enhanced proportion of the diaxial conformer.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1270060411
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