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  • 1
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 802-806 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A six-parameter multiresponse model based on the catalyst aging theory of Wojciechowski (1968) is applied to experimental selectivity data in gas oil cracking. Within the range of conditions studied, the model gave an adequate fit to the data. It was found that the selectivity curves at various cat/oil ratios were contained within optimum and minimum performance envelopes but that the relationships between these envelopes and the selectivity curves were not quite as simple as had previously been reported for a theoretical example (Campbell and Wojciechowski, 1969). The optimum time-on-stream for each of the cat/oil ratios was about one minute. Maximum gasoline production was 59 weight % at 81 weight % total cumulative conversion, resulting in a gasoline efficiency of 72.8%.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 1121-1125 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The time on stream theory of catalyst decay is applied to gas oil cracking selectivity data from a static bed reactor operating with a diffusion limited catalyst. It is found that intraparticle diffusion affects the reactions leading to the disappearance of gas oil to a much greater extent than the reaction leading to the recracking of gasoline and catalyst poisoning. Reasons for this behavior are postulated. It is also found that the overall kinetic order for the rate of disappearance of gas oil is decreased with the result that maximum selectivity occurs at a higher conversion value than for a corresponding diffusion-free catalyst. It is concluded that probably diffusion limitation is not a serious problem with respect to gasoline selectivity in commercial reactors.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
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