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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Physics of Fluids 6 (1994), S. 3267-3275 
    ISSN: 1089-7666
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The surfactant influence on the bubble motion in a Hele–Shaw cell was studied experimentally. In order to differentiate the cases with and without the surfactant influence, the motion of air bubbles and water drops driven by silicone oil was investigated. The water drops contained a predetermined amount of an organic surfactant (sodium dodecyl sulfate), so that the dependence of their motion on the surfactant concentration could be studied systematically. In case of air bubbles in silicone oil, surfactants were likely to have negligible influence, although they might be present as contaminants, and their translational velocities were observed to be close to the prediction of Taylor and Saffman [Q. J. Mech. Appl. Math. 12, 265 (1959)]. The bubble shapes were also in accordance with available theories for a surfactant-free system. The water drops, on the other hand, behaved very differently, in that the translational velocities were smaller by an order of magnitude and their shapes were very unusual. These observations are apparently consistent with those of Kopf-Sill and Homsy [Phys. Fluids 31, 18 (1988)], and the present study suggests that the perplexing observations by them may be due to the influence of surface-active contaminants.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY : American Institute of Physics (AIP)
    Physics of Fluids 4 (1992), S. 2335-2347 
    ISSN: 1089-7666
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The steady motion of a long inviscid bubble displacing a viscous fluid in a capillary tube was first analyzed by Bretherton [J. Fluid Mech. 10, 166 (1961)] in the limit of small capillary number (Ca). While his theoretical prediction for the wetting film thickness left behind the moving front of the bubble showed good agreement with experimental observations for a moderately small Ca, it underpredicted the film thickness when Ca was smaller than about 10−4. In an attempt to resolve this discrepancy, several investigators studied the Marangoni effects of surface contaminants and predicted that the film thickness could be increased by a maximum factor of 42/3 if the surfactant transport is bulk-diffusion controlled. This prediction, however, is limited to the case of a semi-infinitely long bubble. The present study examines the motion of a finite length bubble in the presence of a small amount of surfactants. Both front and rear ends of the bubble are analyzed in the limit of small capillary number. The results indicate that due to the accumulation of the surfactant at the rear end of the bubble, the film thickening effect of the surfactant occurs only when the bubble length is larger than a certain critical value. It is also shown that the total pressure drop to drive the finite bubble through the capillary tube increases linearly with the length of the bubble as long as the bubble length is smaller than the critical value. When the bubble is longer than the critical value, the pressure drop does not increase any longer but remains to be constant. It appears that these results are capable of explaining the experimental observations of Schwartz and co-workers [J. Fluid Mech. 127, 259 (1986)] in which the film-thickening behavior at low Ca was shown to be dependent on the bubble length.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1573-6776
    Keywords: enzymatic modification ; phospholipase A2 ; PUFA ; transesterification ; water activity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: Abstract Phospholipase A2-catalysed transesterification of phosphatidylcholine (PC, 99%) with eicosapentaenoic acid ethyl ester (EPAEE, 95%) was carried out in organic solvent. The maximum yield was 14.3% (w/w). The optimum reaction condition was 50 °C, 48 h, initial water activity 0.25 and molar ratio of PC to EPAEE 1:10 in 5 ml toluene.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 31 (1991), S. 197-203 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Extensional flow of a bicomponent two-layer slot cast coextrusion process has been studied. A Newtonian and an upper-convected Maxwell fluid were considered to be the two layers, respectively, and the two-layer flow was assumed to be steady and isothermal. This choice was made as a simple model for a system which consists of two distinctly different fluids in terms of their extensional behaviors. Present study considered only the draw-down region where the film thickness changes slowly with the distance from the die exit. For this region, asymptotic solutions could be obtained for two limiting cases in which the elasticity effect of the Maxwell fluid layer is small and the applied tension at the take-off is large, respectively. When the elasticity effect is small, the melt thickness and the velocity profiles are exponential as in the case of a Newtonian single-layer flow. When the applied tension is large, on the other hand, the velocity profile is shown to be near linear. Furthermore, the viscoelasticity effect of the Maxwell fluid layer becomes so dominant that it dictates the mechanics of the coextrusion flow even when its flow rate and shear viscosity may be much smaller than those of the Newtonian layer.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 36 (1990), S. 197-206 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A steady, isothermal flow of a two-phase fiber spinning has been studied. To investigate the spinline velocity profile affected by the interaction between two fluids with different rheological properties, a Newtonian and an upper-convected Maxwell fluid were considered to be the core and skin layers, respectively. Unlike the one-dimensional analysis, which has been the typical approach for spinning flows, radial dependency of the flow field was maintained in our analysis. Consequently, a set of partial differential equations were derived for the flow field in the draw-down region where lubrication scalings are applicable. Asymptotic solutions were then obtained for two limiting cases, where the Deborah number of the skin layer is small and the applied axial tension is large. When the Deborah number of the skin layer is small, a velocity correction to the Newtonian profile indicates a strong effect of the flow rate ratio as well as the shear viscosity ratio of the two fluids. For the case of a large applied tension, which is more relevant to industrial practice, very interesting flow behaviors are predicted. In this limit, the viscoelasticity effect of the skin layer is shown to be dominant and dictates the mechanics of the flow even when both its flow rate and shear viscosity may be much smaller than those of the Newtonian core layer. The result also predicts that hoop stress has a negligible effect on the axial velocity profile.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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