ISSN:
0021-8383
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The rate constants and the kinetic parameters of the reaction of phenacyl bromide with mono and disubstituted anilines in ethanol have been determined. The substituent effects on the free energy of activation have been found to be additive. HAMMETT equation for multiple substitution was applied to correlate reactivity with structural parameters. The substituent effect is separated into inductive and resonance effects.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/prac.19723140510
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