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Digitale Medien

Cinétique et mécanisme de la polymérisation de i'acrylamide initiée par le système réadox: Fe3+/complexe organique de Fe(III)/Na2S2O5 (1984)

Cvetkovska, Maja ; Grčev, Toma ; Petrov, Gjuro

New York : Wiley-Blackwell

Die Makromolekulare Chemie 185 (1984), S. 429-439

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Details

ISSN: 0025-116X

Schlagwort(e): Chemistry ; Polymer and Materials Science

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Physik

Notizen: The initiation of acrylamide polymerisation in aqueous media with a redox system of the type Fe3+/organic complex of Fe(III)/Na2S2O2 was studied. Several carboxylated amines containing the iminodiacetate group as a basic structural unit were used as complex forming reagents. A direct relation between complex stability and initiation efficiency was found. The polymerisation kinetics were studied with the most effective intiating system. Several kinetic parameters were determined and an essential relationship between polymerisation behaviour, polymer characteristices and component ratio of the initiation and polymerisation system was found. An attempt was made to explain these results.

Zusätzliches Material: 3 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/macp.1984.021850301

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