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  • 1
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The 12C31P and 13C31P diatomic radicals have been generated by the laser vaporization reaction between carbon and phosphorus which were pressed into a pellet to form the laser target. This method is applicable to a wide range of nonmetallic systems for generating new reactive intermediates which cannot be done with more conventional approaches. The radicals were isolated in neon and argon matrices at 4 K for detailed ESR investigations. The magnetic parameters (MHz) for neon were: g(parallel)=2.0009(3); g⊥=1.9902(3); A(parallel)(31P)=145.0(3); A⊥(31P)=−269.0(2); A(parallel)(13C)=580.0(3); and A⊥(13C)=422.0(3). The argon A and g tensors were virtually indistinguishable from these neon results. Extensive ab initio theoretical calculations were conducted for CP which yielded nuclear hyperfine A values in close agreement with the experimental results. Valence orbital spin populations extracted from the calculated CI wave functions are compared with those determined directly from the ESR hyperfine parameters for 13C and 31P. The observed g shift for CP agreed with the gas phase spin–rotation constant and indicates the presence of a low lying 2πr state that has not been previously observed.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The first spectroscopic study of the diatomic radical BC is reported which confirms previous theoretical predictions of a 4∑− electronic ground state. The nuclear hyperfine interactions (A tensors) obtained for 11B, 10B, and 13C from the electron spin resonance (ESR) measurements are compared with extensive ab initio CI calculations. The BC molecule is one of the first examples of a small high spin radical for such an in-depth experimental–theoretical comparison. The electronic structure of BC obtained from an analysis of the nuclear hyperfine interaction (hfi) is compared to that obtained from a Mulliken-type population analysis conducted on a CI wave function which yields Aiso and Adip results in good agreement with the observed values. The BC radical was generated by the laser vaporization of a boron–carbon mixture and trapped in neon, argon, and krypton matrices at 4 K for a complete ESR characterization. The magnetic parameters (MHz) obtained for 11B13C in solid neon are: g(parallel) =2.0015(3); g⊥ =2.0020(3); D(zfs)=1701(2); 11B: ||A(parallel)|| =100(1); ||A⊥|| =79(1); 13C: ||A(parallel)|| =5(2) and ||A⊥|| =15(1). Based on comparison with the theoretical results, the most likely choice of signs is that all A values are positive.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 110 (1988), S. 6240-6241 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 88 (1988), S. 481-482 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The first spectroscopic results are reported for the 69,71GaAs+ cation radical generated by photoionizing GaAs (g) produced by the pulsed laser vaporization of GaAs (s). The GaAs+ cation was trapped in neon matrices at 4 K for ESR investigations which show the ground electronic state to be 4Σ− in agreement with previously reported theoretical calculations. Components of the gallium A tensors are 69Ga; A⊥=184.2(2), A(parallel)=270 (30) MHz, and for 71Ga A⊥=234.4(2), A(parallel)=345(35) MHz. The unresolved As hfs was estimated to be less than 8 MHz for the perpendicular direction and the molecular g⊥ value as 1.9978(2) with g(parallel) presumably∼2.00. These nuclear hyperfine parameters are used to obtain a description of the valence electronic structure for GaAs+ which can be compared with recent MCSCF/CI theoretical results.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Copenhagen : Munksgaard International Publishers
    Ecology of freshwater fish 9 (2000), S. 0 
    ISSN: 1600-0633
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract – We examined the effects of snorkeling, a commonly used fish observation technique, on the distribution and abundance of benthic macroinvertebrates at both the reach (i.e., 10 m) and patch scale (i.e.,〈 1 m) within a southern Appalachian stream (North Carolina, USA). At the reach scale, we quantified increases in macroinvertebrate drift rates associated with snorkeling and used these values to calculate the percentage of the macrobenthos that drifted out of snorkeled reaches. We also used a simple decay model of macroinvertebrate drift to quantify patch scale effects of snorkeling. The model incorporated size specific macroinvertebrate settling rates to estimate the total number of benthic macroinvertebrates that entered the drift in response to snorkeling disturbance. We found that snorkeling consistently produced significant increases in the number of drifting macroinvertebrates. Nevertheless, these increases comprised a very small percentage (〈1%) of the total number of organisms in the benthos, suggesting that snorkeling probably did not strongly affect macroinvertebrate assemblages at either the reach or patch scale. However, our analyses also indicated that snorkeling had a disproportionate effect on the drift of small ephemeropterans (4–5% entered the drift in response to snorkeling) relative to other macroinvertebrate taxa. Consequently, the microdistribution of early instar mayflies may have been altered within snorkeled reaches. We conclude that snorkeling related disturbance to the benthos should have a minimal effect on the behavior and distribution of most stream fishes at either the reach or patch scale. However, because snorkeling had a substantial effect on the drift of small mayflies, snorkeling may influence the behavior of fishes that depend on early instar mayflies as a primary food resource./〉
    Type of Medium: Electronic Resource
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