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  • 1
    Digitale Medien
    Digitale Medien
    s.l. : American Chemical Society
    Macromolecules 2 (1969), S. 111-117 
    ISSN: 1520-5835
    Quelle: ACS Legacy Archives
    Thema: Chemie und Pharmazie , Physik
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    s.l. : American Chemical Society
    Macromolecules 2 (1969), S. 118-122 
    ISSN: 1520-5835
    Quelle: ACS Legacy Archives
    Thema: Chemie und Pharmazie , Physik
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 9 (1965), S. 1041-1053 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: A procedure for the study of the chemistry of viscose based on ultraviolet measurements of a film of cellulose xanthate has been developed. To illustrate the range of usefulness of the technique, spectra of various compounds formed with cellulose xanthate, including metal salts, organic derivatives, and an acid form, the influence of solvation on several cellulose xanthate compounds, and formation and decomposition curve of cellulose xanthate derivatives are presented. Possible applications of the technique include a study of the acid decomposition of cellulose xanthate, the influence of additives, new derivatives, and the xanthation mechanism. It is also probable that the method can be used in the study of other systems where fast reaction mechanisms are involved and suitable absorption characteristics are present.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 9 (1965), S. 1055-1065 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Formaldehyde reacts reversibly with cellulose xanthate in aqueous acid to form a product having an absorption maximum at 280 mμ and an extinction coefficient of 11,600. The fraction of the original xanthate converted to the formaldehyde form is related to the formaldehyde concentration. The aqueous acid decomposition rate of the formaldehyde derivative is pseudo first-order and is inversely proportional to the formaldehyde concentration. At high acidities the decomposition rate is independent of acid concentration, but the rate decreases with decreasing acidity in the pH range of 1-4. On the basis of the data obtained in these studies, the equilibrium constant for the formation of the formaldehyde derivative was found to be of the order of 10.4.8. The activation energy for the decomposition of the formaldehyde derivative is 18,600 cal./mole.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 9 (1965), S. 1067-1072 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Kinetic equations for the decomposition of S-hydroxymethyl cellulose xanthate in the presence of acid and formaldehyde are derived. The assumed mechanism involves an equilibrium between the S-hydroxymethyl cellulose xanthate and cellulose xanthic acid and xanthate ion. Decomposition appears to proceed via interaction between the cellulose xanthate ion and hydrogen ion which form an activated complex that subsequently decomposes to cellulose and carbon disulfide. The equations derived show the proper dependence on acid and formaldehyde concentrations. An estimate of the equilibrium constant between cellulose xanthate and S-hydroxymethyl cellulose xanthate is calculated from the rate constants.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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