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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 89 (1985), S. 591-600 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 92 (1988), S. 5731-5738 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 95 (1991), S. 5545-5551 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 825-831 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: In this paper a model of charged particle behavior in a low-pressure oxygen plasma is developed, and compared with experimental results. Agreement is excellent. It is demonstrated that the extremely high temperature ((approximately-greater-than)1 eV) of electrons in these plasmas results in diffusion totally dominating the transport of charged species. It is also shown that charged particle recombination on the walls of a quartz reactor is insignificant. Finally, the influence of the electron temperature profile must be fully considered for accurate results. This work complements an earlier model of radical behavior in these plasmas. Both are needed to fully understand materials modification in these plasmas, which has been shown to involve a synergism between radicals and charged species.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 72 (1992), S. 870-878 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A one-dimensional mass continuity equation was used to model a low pressure, high radical concentration, nonisothermal oxygen afterglow reactor. This type of afterglow system has never been modeled despite its broad range of uses: low temperature passivation of polycrystalline silicon thin film transistors, chemical vapor deposition and etching, ceramic superconductor oxidation, growing silicon dioxide surfaces, and surface cleaning including the removal of photoresist films. It was shown that the model, with no adjustable parameters, yielded very good agreement with experimental measures of O-atom flux. The temperature profile and charged particle concentration profile used in the model were measured experimentally. The model was manipulated to study the influence of temperature profile, pressure, homogeneous and heterogeneous kinetics, O-atom generation, and flow rate on the afterglow plasma. Some results were surprising, such as the finding that the value and position of maximum O-atom concentration can be readily manipulated. The model was also used to assess the validity of a frequently used probe of O-atom flux.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 66 (1995), S. 171-175 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: The initial operation of a Calvet-type calorimeter is reported. The instrument has been designed specifically to study lithium and lithium compound reactions with water at an elevated temperature. Additionally, the calorimeter test section incorporates an environment that resembles actual application conditions. Calibration procedures are explained for three important parts of the instrument, including (1) introduction of the water sample, (2) analysis of the effluent gas, and (3) measurement of the heat of reaction. Ten measurements of the heat of the lithium oxide-water reaction yielded values from 110 to 140 kJ/mol H2O and averaged 124 kJ/mol H2O. The average is in perfect agreement with the theoretical heat value computed utilizing JANAF thermochemical data. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 59 (1986), S. 769-779 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The sintering of sputter-produced, silica-supported platinum thin films was studied using electron microscopy and x-ray diffraction following treatments in both reactive (ethylene oxidation—O2+C2H4) and nonreactive atmospheres (vacuum, O2, N2, C2H4, CO2, H2O). Sintering behavior in nonreactive atmospheres (thermal sintering) was found to be insensitive to the gas phase and was a function of temperature only. Changes in film structure following thermal sintering were not dramatic and were readily explained by conventional models. In contrast, sintering in reactive atmospheres was found to be a strong function of temperature and the O2/C2H4 ratio. Over a relatively narrow temperature range (770–970 K), the surface was found to be dramatically restructured with plantinum completely stripped from some areas and large particles forming in others. This type of sintering (reaction-enhanced sintering) possibly results from the interaction of homogeneously formed radicals with the metal surface to form metastable mobile intermediates.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 58 (1985), S. 1943-1949 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A modified model of relaxation for systems containing both a magnetic field and an electric field gradient is presented. This model is used to explain the 57Fe Mössbauer spectra of small iron χ-carbide particles supported on two types of high surface area carbon. On the basis of this model, it is concluded that χ-carbide particles interact weakly with graphitic carbon, but very strongly with nearly amorphous carbon. On the nearly amorphous carbon, the particles may, in fact, have an unusually high surface-to-volume ratio.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 56 (1985), S. 2312-2318 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A new calorimeter of the heat-flow type designed to measure the differential heats of adsorption of gases on high surface area solids (e.g., catalysts) is described. Heat flow is measured using conventional thermopiles; the signals from which are amplified, digitized, and then sent to a laboratory computer for ease of data handling and analysis. The instrument allows conventional isotherm and heat data to be collected concomitantly. Other useful information obtained includes qualitative data regarding the rate at which processes take place, the total amount of gas chemisorbed, and the integrated value of the heat of adsorption. The instrument is capable of operating at temperatures from 273 to 373 K. One major advance over previous designs is that the dosing gas is allowed to thermally equilibrate before entering the sample chamber. The results of a simple study of the differential heats of adsorption of oxygen on a high surface area carbon material are presented. This study demonstrates the reliability and utility of the instrument.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial & engineering chemistry research 31 (1992), S. 193-204 
    ISSN: 1520-5045
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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