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  • 1
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 217 (1968), S. 949-949 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] From the viscosity measurements, made with a Ubbelohde viscosimeter, the reduced specific viscosity was calculated as ijgf = (te -.)/.. c(dl./g) A Sofica 40,000 A was used to measure the light-scattering value Vv in mA, which is the intensity of the vertical polarized scattered light transmitted ...
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The oxidation of 2-mercaptoethanol with molecular oxygen in water with cobalt(II)phthalocyanine-tetra-sodium sulfonate attached to poly(vinylamine) has been investigated. Specially attention was paid to the effect of pH and chain dimensions on polymer activity. The polymer catalyst possesses a large conformational freedom at neutral pH, but at higher pH a shrinkage of the polymer coil occurs and diffusion limitations cannot be excluded. The catalyst shows an enzyme-like behaviour in the autoxidation of thiol. Overall activation energies appear to decrease with increasing pH. At pH = 7.4, Ea = 61 KJ mole−1; at pH = 9.5, Ea = 3 KJ mole−1. Electrostatic effects are of major importance in the chemical reactivity since they affect the local thiol-anion concentration in the close vicinity of the polymer attached oxidation sites.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1573-2614
    Keywords: Equipment ; automatic blood pressure ; Monitoring ; blood pressure ; Blood pressure ; measurement ; Measurement techniques ; blood pressure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science , Medicine
    Notes: Abstract The Cortronic APM 770 (Cortronic, Ronkonkoma, NY) is a commercial device that claims to measure blood pressure noninvasively and continuously with the use of a standard blood pressure cuff. The aim of our study was to assess the performance of the continuous-mode blood pressure readings of the Cortronic during anesthesia and surgery. We recorded blood pressure in 5 patients bilaterally. An intraarterial pressure (IAP) curve was recorded from 1 arm and the Cortronic pressure curve (CPC) was recorded from the other. For statistical analysis the period between 2 Cortronic recalibrations was defined as the intercalibration interval. The duration of these intervals ranged from 20 to 0.5 minutes. Four paired samples were drawn from each interval. The first sample in an interval represented the recalibration blood pressure; the other samples represented the continuous blood pressure. A total of 1,232 samples were taken, of which 308 were recalibration. The median of the differences and the 2.5th and 97.5th percentile limits of agreement were determined. Their respective values for diastolic and systolic recalibration measurements were 5, −17, and 34 mm Hg, and 6, −12, and 38 mm Hg. Their values for continuous measurements were 4, −23.5, and 32 mm Hg, and 6, −30, and 70 mm Hg. Changes in CPC were evaluated against changes in the corresponding IAP by plotting them in 4-quadrant graphs. In these graphs the Spearman rank correlations were betweenr=−0.17 andr=0.01. We observed opposite CPC and IAP trends on 24 occasions during this study. We performed a simple simulation study to better understand the measurement method of the Cortronic. The study showed a positive relationship between pulsation volume and CPC amplitude, and between pulsation rate and CPC amplitude. We conclude that during anesthesia and surgery continuous-mode blood pressure readings of the Cortronic are unreliable, and suggest that the phenomenon of the two pressures' moving in opposite directions is inherent to the measurement principles of the device.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 2353-2362 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Copolymers of vinylamine and vinylalcohol were prepared by hydrolysis of poly(N-vinyltert-butylcarbamate-co-vinylacetate) in 1:1 v/v % ethanol/HCl mixtures at room temperature. Reactivity ratios of the monomers N-vinyl-tert-butylcarbamate (1) and vinylacetate (2) were calculated from monomer feed and copolymer composition data, according to the methods of Fineman-Ross and Kelen-Tüdös, yielding r1 = 1.14 ± 0.05, r2 = 0.47 ± 0.07, and r1 = 1.12 ± 0.07, r2 = 0.46 ± 0.03, respectively. From these values the average sequence length distribution of monomer units was derived showing that in the raction of N-vinyl-tert-butyl carbamate and vinylacetate nearly Bernouillian (i.e., purely random) copolymers are formed, with a slight tendency toward alternation.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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