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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 110 (1977), S. 491-499 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Reactions with Monohydrazones of Dicarbonyl Compounds, IV. New Syntheses of Pyrroles and PyrrolinesKetones and aldehydes with an active methylene group condense easily with monohydrazones of glyoxal (1 + 2 → 3). The hydrazonoethylidene derivatives thus obtained can be reduced to give pyrroles, pyrrolines, pyrrolidines, or N-aminopyrroles.
    Notes: Methylenaktive Ketone und Aldehyde lassen sich mit Monohydrazonen des Glyoxals zu Hydrazonoethyliden-Derivaten umsetzen (1 + 2 → 3). Durch Reduktion dieser Produkte sind Pyrrole, Pyrroline, Pyrrolidine sowie N-Aminopyrrole darstellbar.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 111 (1978), S. 1564-1577 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Reactions with Monohydrazones of Dicarbonyl Compounds, VI: Syntheses of 4-Oxocarboxylic Acids and their Esters by Means of α-Hydrazonoaldehydesα-Hydrazonoaldehydes (11) can be prepared by oxidation of ketone hydrazones 14 with selenium dioxide or by coupling of enamines 12 with a diazonium salt 13. The α-hydrazonoaldehydes 8, 11 react with (ethoxycarbonylmethylene)triphenylphosphorane (15) or with carboxylic acid esters 17 in the presence of a base to give hydrazones of unsaturated 4-oxocarboxylic acid esters (16). By hydrolytic cleavage or by reductive hydrolysis unsaturated or saturated 4-oxocarboxylic acid esters (18 and 19, resp.) are obtained. Hydrolysis of hydrazonoethylidene derivatives of ketones leads to the formation of 4-oxocarboxylic acids (28 → 29).
    Notes: α-Hydrazonoaldehyde (11) sind aus Ketonhydrazonen 14 durch Selendioxid-Oxidation oder durch Kupplung von Enaminen 12 mit Diazoniumsalzen 13 darstellbar. Mit (Ethoxycarbonylmethylen)triphenylphosphoran (15) oder mit Estern 17 in Gegenwart von Basen lassen sich α-Hydrazonoaldehyde 8, 11 zu Hydrazonen ungesättigter 4-Oxocarbonester (16) umsetzen. Durch Hydrolyse oder reduktive Hydrolyse erhält man ungesättigte bzw. gesättigte 4-Oxocarbonester (18 bzw. 19). Hydrazonoethyliden-Derivate von Ketonen ergeben bei der Hydrolyse 4-Oxocarbonsäuren (28 → 29).
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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