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  • 1
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 35 (1995), S. 441-459 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The steady melting of several amorphous and semicrystalline polymers during spin welding is analyzed by solving a simplified set of momentum and energy balance equations, assuming a shear-rate and temperature-dependent viscosity. A numerical model is developed for predicting the flow field and the temperature distribution in the molten film. It is shown that the steady melting rate of the thermoplastic solid is affected by the variable viscosity, by the pressure applied on the parts to be joined, and by a balance between the viscous heat generation in the melt and the convection of colder material into the molten film. The convection of heat in the outflow direction is shown to have a much smaller effect on the melting process.
    Additional Material: 21 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 32 (1992), S. 1147-1162 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The steady melting of rectangular thermoplastic bars in contact with hot surfaces is analyzed by solving a simplified set of the momentum and energy balance equations, assuming a temperature and shear-rate dependent melt viscosity. A numerical model is developed for predicting the flow field and the temperature distribution in the solid and molten regions of the bar and the location of the solid/melt interface. Computer simulations show that the steady melting rate of the thermoplastic solid is mainly affected by the temperature sensitivity of the melt viscosity, by the pressure applied on the end of the bar, and by a balance between heat conduction and the convection of colder material into the molten region. For the amorphous and semicrystalline polymers considered, heat convection in the outflow direction of the molten material, viscous dissipation, and shear-thinning of the melt viscosity have a much smaller effect on the melting process. These results provide an insight into conduction-induced melting with forced melt removal caused by pressure-induced flow; they also provide a basis for developing a transient model for the hot-tool welding process.
    Additional Material: 19 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 35 (1995), S. 877-892 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Isothermal experiments on gas-assisted displacement of viscoplastic liquids in tubes show that a liquid coating remains on the tube wall. The thickness of this coating approaches 0.35 of the tube radius at high gas penetration rates, the asymptotic limit previously observed for Newtonian liquids. At low gas penetration rates, the viscoplastic coating is much thinner than its Newtonian counterpart. During the displacement process, the gas front moves faster than the liquid front and, prior to blowout, it rapidly accelerates as the amount of liquid downstream of the gas is depleted by the liquid coating. Based on these observations, a simple isothermal model is developed to describe the gas-liquid dynamics. This model provides an insight into the gas-assisted injection molding process in which the injection of molten plastic into a mold is assisted by a pressurized gas. In particular, the results show that the wall thickness around the hollow cores in gas-assisted parts is set during processing by the solid skin and a thick molten layer. The thickness of the molten layer depends on the gas penetration rate and the viscous behavior of the molten plastic. By coupling the isothermal model with a one-dimensional heat-transfer analysis, the gas penetration rate is shown to be several orders of magnitude higher than the plastic freezing rate, so that most of the heat transfer between the melt and the gas occurs after the mold is filled.
    Additional Material: 18 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 453-459 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An investigation was undertaken to study the extrusion behavior of composite systems. A compound made up of approximately 50 percent ceramic particulates by volume dispersed in a high molecular weight thermoplastic polymer was characterized by measuring the shear viscosity on an Instron capillary viscometer. The experimental data indicated that the ceramic composite exhibited an apparent yield stress. As a result, an expression that was previously shown to provide flexibility for describing a yield stress at low rates of deformation could explain the viscosity of the ceramic composite. The expression was then applied to the flow analysis of both a “rod” and a “slit” die in an extrusion process, and the derived equations adequately correlated experimental volumetric flow rate us. Pressure drop data obtained on a laboratory extruder.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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