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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 87 (2000), S. 8220-8220 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The "electron fraction" model for electron microprobe quantification described by Pingitore et al. [J. Appl. Phys. 86, 2790 (1999)] does not, as claimed, rest upon more rigorous physical foundations than the models used in this field for several decades, but actually is less rigorous. Comparisons with the "first approximation" of Castaing [R. Castaing, Ph.D. thesis, University of Paris (1951)] are irrelevant since this is never used in practice. Also, the observation that characteristic x-ray intensities are constant for different isotopes of the same element is not, as suggested, evidence that the physical basis of the orthodox approach is unsound. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 306 (1983), S. 172-173 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Most determinations of REE in chondritic phosphates4,5 do not discriminate between apatite and merrillite, owing to difficulty in separation. However, Ebihara and Honda2 attempted to utilize grain-size differences for this purpose (other physical properties being closely similar). Phosphate ...
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 221 (1969), S. 943-944 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Table 1. ELECTRON PROBE MICROANALYSES (J. M. HIJNNEX), TENHAM METEORITE, B.M.1935,792 Ringwoodite Purple Bluish-grey Olivine 1 2 3 Si02 38-9 38-7 38-3 FeO 23-4 23-2 23-2 MgO 37-0 38-8 38-6 CaO Nil Nil Nil Total 99-3 100-7 100-1 Column 1 of Table 1 lists an electron ...
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 204 (1964), S. 374-375 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] The results of the electron probe measurements are given in Table 1. The chondrites are listed in order of increasing fraction of metal present. They range from Dhurmsala with 3 per cent of metal2 to Forest City with 24 per cent3 and the average nickel content of the metal ranges from 22 per cent ...
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 198 (1963), S. 777-778 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Profiles showing the distribution of calcium obtained from the measured calcium Ken intensity encountered in traverses across basal lamellae in the two grains are illustrated in Figs. 1 and 2. In the igneous clinopyroxene, the lamellae were sufficiently wide (10-15(0,) for boundary effects due to ...
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 78 (1982), S. 404-412 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract The Cu contents of biotites (av. 880 ppm), amphiboles (16 ppm) and magnetites (160 ppm) from barren intrusions of the Koloula Igneous Complex are significantly greater than the Cu contents of the same minerals from unaltered mineralizing intrusions (av. 23, 6, and 20 ppm respectively). The Cu content of amphiboles from mineralizing intrusions is strongly domain-dependent, with Cu (and chlorine) being depleted in compositional domains that formed during intermittent boiling of hydrothermal fluids. The conversion of pyroxene to amphibole is an unlikely process for the release of Cu. Owing to the differences in Cu contents of biotite, amphibole, and magnetite, mineralizing rock types from the Koloula Igneous Complex are depleted in Cu compared to barren intrusions by 60 ppm, of which 57 ppm is attributable to biotite, 0.5 ppm to amphibole, and 2 ppm to magnetite. Partitioning of the amount of Cu measured here into the fluid phase during boiling is potentially large enough to produce porphyry copper orebodies. The high Cu-contents of minerals from barren rocks suggest that igneous complexes that are hosts for porphyry copper deposits may be anomalously enriched in that metal.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Major-element analyses (by electron microprobe) and copper contents (by ion-probe) are reported for primary biotite, amphibole, magnetite, pyroxene, ilmenite, sphene and secondary biotite from intrusive rocks from mineralizing and barren stocks. The districts studied include Christmas, Globe-Miami, Sierrita and Tombstone, in Arizona; Bingham and Alta, Utah; Ely, Nevada; and Brenda, British Columbia. Amphiboles from barren rocks are relatively iron-rich and display only minor compositional variation. In contrast, amphiboles from mineralizing rocks span the range from magnesio-hornblende to actinolite, commonly even within one grain. Barren intrusions (type B) that are temporally distinct from mineralizing intrusions, and barren intrusions outside areas of known mineralization have higher Cu contents in their constituent minerals than do mineralizing intrusions. Barren intrusions (type A) that are deep-level temporal equivalents of Cu-bearing porphyritic rocks are depleted in copper. This suggests that copper is abstracted from not only the apical portions of porphyries but from parts of the deeper parent intrusions. The Cu contents of biotites (av. 23 ppm) and magnetites (97 ppm) from barren type B intrusions contrast with those from mineralizing intrusions, with biotites containing 7 ppm Cu and magnetites 3 ppm Cu. Primary amphiboles from all intrusive rock types have low copper contents, typically 2 to 5 ppm. In the continental North American deposits, the amount of copper available by liberation from or non-incorporation into amphibole, biotite and magnetite during magmatic crystallization or the early hydrothermal stage is low, perhaps too low to be the sole source of copper mineralization, unless copper is abstracted from large volumes (∼ 100 km3) of rock. These results contrast with a study of the island-arc porphyry copper at Koloula, Guadalcanal, where it was argued that sufficient copper for mineralization could have been abstracted from relatively small volumes of host rocks that originally contained as much Cu as the contemporaneous barren rock types.
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 1438-1168
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Description / Table of Contents: Zusammenfassung Zwei Gruppen komagmatischer Intrusivkörper können im Bereich der Molybdän-Lagerstätte Climax, Colorado, unterschieden werden: Mineralisierende Intrusiva, die Stammagmen für Molybdän-Erzkörper darstellen, und erzfreie Intrusiva. Magmatische Biotite in mineralisierenden Intrusiva sind hydrothermalen Biotiten insofern ähnlich, als sie einen größeren Anteil von Si-angereicherten und Ti-verarmten Bereichen enthalten als magmatische Biotite in erzfreien Intrusiva. Ein ähnlicher Trend von Si-Anreicherung, die mit Ti-Verarmung korreliert werden kann, ist auch in Biotiten aus der Porphyry-copper-Lagerstätte Bingham bekannt geworden. Derartige Trends werden auf Entmischung von Dampfphasen in Zusammenhang mit der Mineralisation zurückgeführt. Molybdän-Konzentrationen von magmatischen Biotiten in Climax wurden mit der Ionensonde bestimmt und zeigen in mineralisierenden und erzfreien Intrusiva ähnliche Werte, i.e., 40 p/g bzw. 33 gg/g. Diese Werte liegen in derselben Größenordnung wie Kupferkonzentrationen in magmatischen Biotiten aus vererzten und erzfreien (Typ A) Intrusionen im nordamerikanischen Porphyry-copper-Lagerstätten (Hendry et al., 1985). Diese Kupfer- und Molybdänwerte sind um den Faktor 10 niedriger als Kupferkonzentrationen, die man gewöhnlich in magmatischen mafischen Phasen in erzfreien (Typ B) Granitsystemen im südwestlichen Pazifik und Australien nachgewiesen hat. Diese sind zeitlich einer anderen Entstehungsperiode zuzuordnen als die erzbildenden Vorgänge, und dies stimmt wiederum mit der magmatisch hydrothermalen Entstehung der Lagerstätten von Climax überein, wie sie vonWhite et al. (1981) vorgeschlagen worden ist.
    Notes: Summary At Climax, comagmatic igneous intrusions can be subdivided into two groups, mineralizing stocks which are parent intrusions for Mo orebodies and barren stocks. Magmatic biotites in mineralizing stocks are similar to hydrothermal biotites in that they contain a greater proportion of Si-enriched and Ti-depleted compositional domains than do magmatic biotites in barren stocks. A similar trend of Si-enrichment correlated with Ti-depletion is also recorded in biotites from the Bingham porphyry copper deposit. Such trends are attributed to vapour exsolution associated with mineralization. Mo concentrations of magmatic biotites, as determined by ion-probe analysis, from mineralizing stocks (av. 40 gg/g) and barren stocks (av. 33 μ/g) at Climax are similar, being in the same order of magnitude as magmatic biotite Cu concentrations in mineralizing and barren (type A) intrusions in North American porphyry copper deposits (Hendry et al., 1985). These Cu and Mo values are more than a factor of 10 lower than Cu concentrations commonly recorded in magmatic mafic phases in barren (type B) South West Pacific and Australian granitic systems that are temporally distinct from mineralizing events, and are consistent with the magmatic-hydrothermal origin for the Climax deposits proposed by White et al. (1981).
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    X-Ray Spectrometry 2 (1973), S. 69-74 
    ISSN: 0049-8246
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Pulse pile-up, dead time, escape peaks, background, and peak overlap in Si(Li) spectra are discussed in relation to microprobe analysis, and procedures for carrying out the necessary corrections for quantitative analysis of elements of atomic number 11 to 30 are described. The accuracy is generally comparable with that obtained with crystal spectrometers, though the limit of detection (about 0.1%) is higher.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    X-Ray Spectrometry 3 (1974), S. 149-150 
    ISSN: 0049-8246
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Twenty-five new measurements of Kβ/Kα X-ray intensity ratios for elements in the atomic number range 20 to 30 confirm other recent evidence that the variation with atomic number in this region is much less than previously thought, but there is still some disagreement for atomic numbers above 27. A table of recommended values is given.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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