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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 1931-1933 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A compound Nd5Co21B4 belonging to the series Rm+nCo5m+3nB2n with m=3, n=2 has been synthesized by melt spinning. The crystal structure and magnetic properties of the compound have been studied by means of x-ray diffraction and magnetic measurements. The compound crystallizes in a hexagonal structure with space group P6/mmm. The Curie temperature, the saturation moment, and the planar anisotropy field of the compound are 570 K, 31.1 μB/f.u., and 861 kOe, respectively. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 88 (2000), S. 4241-4244 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The ternary intermetallic compound Gd3Fe28.2W0.8 with a Nd3Fe29−xTix-type structure was synthesized with W as a stabilizing element, and its crystal structure and magnetic properties were investigated by means of x-ray powder diffraction and magnetic measurements. The space group of Gd3Fe28.2W0.8 is A2/m with lattice parameters a=10.5812 Å, b=8.5338 Å, c=9.6986 Å, and β=96.86°. Rietveld refinement of the crystal structure reveals that W atoms occupy exclusively three crystallographic positions (4g, 4i3, 4i4) with only one neighboring Gd atom. The preferential occupation of W atoms can be understood in terms of the site volume and enthalpy of mixing. The compound exhibits a planar magnetocrystalline anisotropy perpendicular to the [102] direction. The Curie temperature Tc, saturation moment Ms, and anisotropy field HA are 502 K, 38.6 μB/f.u., and 7.5 T, respectively. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 80 (1996), S. 336-341 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The crystal structure and magnetic properties of LaCo13−x−yFexSiy compounds were investigated by means of x-ray powder diffraction and magnetization measurements. The substitution of Si for Co induces an order–disorder transition from the cubic NaZn13-type to its tetragonal derivative structure, while the substitution of Fe for Co does not induce such a phase transition. After annealing treatment, the homogeneous range of the cubic phase is narrowed and that of the tetragonal phase is extended. From crystallographic and thermodynamic points of view, the sta- bility of the cubic and the tetragonal phases is discussed. The measured magnetic moment of LaCo13−x−yFexSiy coincides well with the theoretical prediction based on the magnetic valence model. Within the framework of this model, LaCo13−x−yFexSiy compounds can be considered as strong ferromagnets and their magnetic moment can be theoretically predicted. The composition dependence of Curie temperature is discussed within the mean field approximation. At higher iron concentration the decrease of Curie temperature with Fe concentration might be attributed to the increase of the number of antiferromagnetically coupled Fe–Fe pairs and the decrease of the ferromagnetic coupling between transition metal atoms. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 70 (1997), S. 1900-1902 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The structural and electronic transport properties of ABO3-type compounds La2/3−xRxCa1/3MnO3(R=Pr, Nd, Sm, Eu, Gd, Tb, Dy, Y, Er, and Tm) with a fixed tolerance factor of t=0.91137 is studied. Similar structure deformation, characterized by the nearly constant average Mn–O, A–O distances and Mn–O–Mn bond angles, is observed in different compounds. The metal–semiconductor transition shows a strong R dependent feature. The transition temperature decreases monotonously from 187 to 77.6 K as R varies from Tm to Pr, with a corresponding maximum resistivity ranging from 2.34 to 6.17×104 Ω cm. Very different magnetoresistance effects are also observed in this series of compounds. By assuming the presence of inhomogeneous local lattice distortions due to ions with different sizes at A sites and their mismatch with B ions, the lattice effects can be understood qualitatively. © 1997 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 82 (1997), S. 4687-4689 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Magnetism of bulk La1/3Nd1/3Ca1/3MnO3 with a magnetoresistance ratio as high as −96% in a field of 0.67 T is investigated. Two shoulders are observed on both thermal magnetization curves and magnetization isotherms. A magnetic inhomogeneity model, i.e., simultaneous occurrence of ferromagnetic La-rich domains and nonferromagnetic Nd-rich domains in the compound, is proposed. The model gives a satisfactory explanation for the experimental results. It is argued that a field-induced magnetic transition occurs in the Nd-rich phase and the coexisting La-rich phase can promote the magnetic transition. © 1997 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The thermal diffusivity of bulk and epitaxial layer samples of the giant magnetoresistance compounds Nd0.67Sr0.33MnO3−δ and La0.67Ca0.33MnO3−δ is investigated in a comparative study for temperatures between 35 and 350 K in order to detect preparational differences and to correlate the thermal transport with magnetization M and resistivity ρ. We find for Nd–Sr an anomaly of the heat diffusivity D near 145 K (80 K La–Ca) which we attribute to a temperature-induced canted metal to AFM insulator transition and a second anomaly in D(T) near 250 K (300 K) which we assign to the transition to paramagnetism. The low-temperature anomaly can be a step of up to five times in the heat conductivity, which makes these compounds potential magnetic field activated heat switches, as this transition can also be induced by a magnetic field. © 1998 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The antiferromagnetic BaCo0.9Ni0.1S2−y and the paramagnetic CuIr2S4 Mott systems show an inverse conductivity behavior, i.e., the metallic phase occurs at low or high temperatures, respectively, which also suggests inverse behavior in other transport properties. In this contribution we present magnetization data, conductivity, thermal conductivity, and Seebeck effect in the temperature range 4.2 K〈T〈350 K and in particular through the metal-insulator transition at TMI. We recover the anomalies in χ(T),σ(T), which are discussed using Jahn-Teller and anti-Jahn-Teller models; also, we compare the anomalies in σ(T), S(T), and of the heat conductivity κ(T) at TMI. In particular, for BaCo0.9Ni0.1S1.95, we find a step in κ of almost one order of magnitude (times 6) and a large pressure shift, ≤−24 K/kbar, which makes this material a potential pressure activated heat switch, while CuIr2S4 shows a small step of κ (times 1.2) and a pressure shift of +2.8 K/kbar. © 1998 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 85 (1999), S. 3619-3622 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Structural, magnetic, and transport properties of ABO3-type La0.7Ca0.3Mn0.96(Al1−xInx)0.04O3 are investigated. Different structure deformation from that in the A-site doping, characterized by the synchronous variation of the lattice constants b with c/(square root of 2) versus the content of In in the compounds, is observed. The metal–semiconductor transition shows a strong In content dependence. The transition temperature decreases monotonously from 180.7 to 103.4 K as x varies from 0 to 1, with a corresponding maximum resistivity ranging from 2.9 to 410.8 Ω cm. The magnetoresistive properties of the materials are strongly affected by the size mismatch between A- and B-site ions, and a relation similar to that presented by Hwang et al. [Phys. Rev. Lett. 75, 914 (1995)] is observed though controlling of the tolerance factor, is realized by B-site doping. © 1999 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 64 (1994), S. 1650-1652 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Tetragonal LaCo13−xSix compounds have been obtained by annealing cubic LaCo13−xSix compounds. The space group for the tetragonal structure is I4/mcm. Atomic ordering occurs in the tetragonal LaCo13−xSix compounds, i.e., Si atoms show a strong preference for occupying a specific crystallographic position. The tetragonal LaCo13−xSix compounds are ferromagnetic with Curie temperatures higher than 900 K. The magnetic moment per Co atom in the tetragonal LaCo13−xSix compounds decreases with Si content, which can be explained by the rigid-band model. The tetragonal LaCo13−xSix compounds are expected to be promising candidates for permanent magnets purpose.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 69 (1996), S. 424-426 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A magnetoresistance ratio as high as −96% in a low field of 0.67 T is achieved in bulk La1/3Nd1/3Ca1/3MnO3. The magnetization exhibits a transition from a low moment state to a high moment state with decreasing temperature, accompanied by a thermal hysteresis of the magnetization. The magnetic transition might be an order-order transition and would be responsible for the observed giant magnetoresistance effect in the compound at low field. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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