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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 68 (1993), S. 291-305 
    ISSN: 1573-2932
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Transport of volatile hydrocarbons in soils is largely controlled by interactions of vapours with the liquid and solid phase. Sorption on solids of gaseous or dissolved compounds may be important. Since the contact time between a chemical and a specific sorption site can be rather short, kinetic or mass-transfer resistance effects may be relevant. An existing mathematical model describing advection and diffusion in the gas phase and diffusional transport from the gaseous phase into an intra-aggregate water phase is modified to include linear kinetic sorption on gas-solid and water-solid interfaces. The model accounts for kinetic mass transfer between all three phases in a soil. The solution of the Laplace-transformed equations is inverted numerically. We performed transient column experiments with 1,1,2-Trichloroethane, Trichloroethylene, and Tetrachloroethylene using air-dry solid and water-saturated porous glass beads. The breakthrough curves were calculated based on independently estimated parameters. The model calculations agree well with experimental data. The different transport behaviour of the three compounds in our system primarily depends on Henry's constants.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 2491-2502 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A model is presented that is focused on the drying kinetics of single wood chips as a function of time and external conditions, such as temperature, pressure and velocity of the superheated steam. A multiphase and 2-D approach was used to model the coupled transport of water, vapor, air and heat in anisotropic hygroscopic porous media. The model was verified by drying experiments where measurements of the average moisture content, center temperature and pressure in a single wood chip could be performed simultaneously. A comparison between the calculations and the measurements showed that the drying behavior was well predicted. The drying can be divided into three stages: a heat-up period when condensation on the surface initially increases the moisture content; a period of constant drying rate when the external heat transfer controls the drying rate; and a period of decreasing drying rate when the drying is controlled by internal mass transfer. Many interesting features of the drying could be assigned to the strong anisotropicity of wood, which makes a 2-D model necessary.
    Additional Material: 18 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 43 (1997), S. 2889-2902 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A model for a pneumatic-conveying dryer is presented, with the focus on the superheated steam drying of wood chips, although it can also be used for other porous materials and drying media. It includes a comprehensive 2-D model for the drying of single wood chips, which accounts for the main physical mechanisms occurring in wood during drying, including coupled transport of water, air, vapor and heat. This model allows for features such as initial condensation and flashing at the outlet, as well as the falling rate period when the drying is controlled by internal transport. External drying conditions in the dryer are calculated by applying mass, heat and momentum equations for each incremental step in dryer length. A plug-flow assumption is made for the dryer model, and single-particle and dryer models were solved iteratively. The irregular movement and nonspherical shape of wood chips are accounted for by measuring drag and heat-transfer coefficients.Model calculations illustrate the complex interactions among steam, particles, and walls that occur in a flash dryer. The drying rate, the slip velocity, and temperature vary in a complex manner through the dryer, necessitating the use of a comprehensive single-particle model, as in this case. Previous experimental data on the drying of bark chips in a pilot dryer was used to verify the model. The predicted temperature and pressure profiles, as well as the final moisture content of the material, agreed well with the measurements. Thus, the model provides a useful tool for the design and scale-up of pneumatic-conveying dryers. Effects of steam and material properties on the drying were investigated with different design parameters.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 31 (1985), S. 1406-1407 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 27 (1981), S. 1032-1035 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 686-690 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 31 (1985), S. 518-519 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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