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  • 1
    Electronic Resource
    Electronic Resource
    Different strong metal-support interaction effects on rhodium/titanium dioxide and platinum/titanium dioxide catalysts (1986)
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 90 (1986), S. 4330-4333 
    Details
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1021/j100409a021
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Modification of the catalytic properties of sulfated zirconia by addition of metal promoters (1995)
    Springer
    Catalysis letters 32 (1995), S. 253-262 
    Details
    ISSN: 1572-879X
    Keywords: alkane isomerization ; sulfated zirconia ; strong acid catalysts ; solid acids ; Fe-Mn-SO4/ZrO2 ; Ni-SO4/ZrO2
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract We have studied the effects of promoting sulfated zirconia catalysts by addition of transition metals. We have found that the addition of Ni causes an activity enhancement comparable to that caused by the addition of Fe and Mn. The TPD/DRIFTS results show that the catalytic activity does not correlate with either Brønsted or Lewis acidity. The high isomerization activity of these catalysts is explained in terms of a bifunctional mechanism in which the metal promoters are responsible for an enhancement in the surface concentration of olefins rather than an enhanced acidity.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00813219
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    Ammonia decomposition on polycrystalline Pt at pressures between 1.3 and 93 kPa (1985)
    Springer
    Reaction kinetics and catalysis letters 28 (1985), S. 407-410 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Измерена кинетика разложения аммиака на поликристаллической Pt в интервале температур 600–1700 К и при давлениях от 1,3 до 93 кПа, которая подчиняется уравнению Пангмюра-Хиншельвуда для скорости мономолекулярной реакции. Это уравнение скорости, как уже ранее установлено, соответствует данным в том же интервале температур, но для давлений от 2 до 1400 Па.
    Notes: Abstract The kinetics of ammonia decomposition on polycrystalline Pt at temperatures between 600 and 1700 K and at pressures between 1.3 and 93 kPa were measured and correlated with a Langmuir-Hinshelwood unimolecular reaction rate expression. This rate expression had previously been shown to fit data in the same temperature range for pressures between 2 and 1400 Pa.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02062973
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    Paper (German National Licenses)
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  • 4
    Electronic Resource
    Electronic Resource
    Direct catalytic synthesis of ethylene from methane (1985)
    Springer
    Reaction kinetics and catalysis letters 28 (1985), S. 431-435 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Исследован синтез этилена из метана на мультифункциональном катализаторе. Полагается, что для получения этиленанеобходимо образование активного предшественника, образующегося высаждением углерода.
    Notes: Abstract Ethylene synthesis from methane has been studied over multifunctional catalysts. It is proposed that the formation of an active precursor, produced by carbon deposition, is necessary for ethylene production to occur.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02062977
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    Paper (German National Licenses)
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  • 5
    Electronic Resource
    Electronic Resource
    Characterization of strong metal-support interaction in Pt/TiO2 catalysts by thermal programmed desorption of benzene (1986)
    Springer
    Reaction kinetics and catalysis letters 31 (1986), S. 145-149 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Взаимодействия на Pt/TiO2 после ВТВ были изучены на примере ТПД бензола. Детектировали смещения температур десорбции после ВТВ. Они приписываются электронным и морфологическим изменениям.
    Notes: Abstract The Pt−TiO2 interaction after HTR was studied by the TPD of benzene. Shifts in desorption temperatures are detected after HTR. They may be ascribed to electronic and morphologic changes.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02062525
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  • 6
    Electronic Resource
    Electronic Resource
    Characterization of active species in alumina and silica supported CuCl2 catalysts by EPR (1988)
    Springer
    Reaction kinetics and catalysis letters 36 (1988), S. 223-227 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract В предыдущей статье [1] полагали, что частицы Cu2+, взаимодействующие с носителем, вызывают повышение активности катализаторов CuCl2, используемых в реакции оксигидрохлорирования метана (CH4+HCl+O2→ хлорметаны). Эти частицы детектировали на носителях Al2O3 и TiO2, но не были обнаружены на SiO2. Приводятся результаты исследований ЭПР, которые дают непосредственную характеристику этих частиц и хорошо согласуются с наблюдаемыми изменениями активности.
    Notes: Abstract In a recent paper [1] we proposed that a Cu2+ species interacting with the support was responsible for maintaining the catalytic activity of CuCl2 catalysts used in the methane oxyhydrochlorination reaction (CH4+HCl+O2→ chloromethanes). This species was detected on Al2O3 and TiO2 supports but it did not appear on SiO2. In this paper we report EPR results which provide a direct characterization of this species and correlate well with the observed trends in activity.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02071168
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    Paper (German National Licenses)
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