ISSN:
0001-1541
Keywords:
Chemistry
;
Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Process Engineering, Biotechnology, Nutrition Technology
Notes:
A process for synthesis of ultrafine ceramic particles using a high-temperature flame is described. Thermodynamic calculations for the Si-C-O-H system were performed using a computer program for calculation of complex chemical equilibrium compositions. Possible synthesis of ultrafine SiC partcles using Si, SiO, and SiO2 powders (1.0-3.0 μm) as Si sources was investigated using an electric furnace (5 kW) at 2,018 K. Particle products were characterized mainly by X-ray diffraction analysis, field emission scanning electron microscopy, and thermogravimetry-differential thermal analysis. Ultrafine particles (18-29 nm) of cubic SiC (β-SiC) could be produced through Si + CH4, SiO + CH4 and SiO2 + CH4 reaction systems, respectively. The effect of hydrogen addition on the synthesis of SiC was also investigated. Ultrafine particles of 96.0% SiC selectivity were obtained when H2 was added to the SiO + CH4 reaction system, and the CH4/SiO molar ratio in this case was 2.0.
Additional Material:
10 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/aic.690431308
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