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  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 191 (1990), S. 881-889 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Ultrasound measurements (at four different frequencies) in the range 15 MHz-75 MHz corresponding to a low frequency pulse technique were made on polypropylene (PP) films of different draw ratios, λa = 1,0, 2,8, 4,9 and 5,8. Process-dependent properties such as draw ratio (and/or thickness), quenching and annealing are functions on which attenuation depends. The logarithm of attenuation for all the samples increases almost linearly with frequency (an instrumental parameter). Such linearity is not observed when looking into the dependence of attenuation on draw ratio or thickness. This is explained in terms of the structural and morphological nature of the samples. The variation of attenuation with draw ratio indicates an exponential increase at frequencies greater than 17 MHz. The increase is very sharp at frequencies of 60,11 and 71,00 MHz. At a frequency of 16,58 MHz, a gradual linear increase in attenuation is observed with draw ratio. On the other hand, as expected, the converse situation of these observations is noted in the dependence of attenuation on film thickness.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 181 (1990), S. 67-74 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Es wurden Untersuchungen über Molekulargewichtsänderungen an physikalisch bei Raumtemperatur gealterten isotaktischen Polypropylenfilamenten (iPP) mit Hilfe der Hochtemperaturgelpermeationschromatographie (HTGPC) durchgeführt. Das Ergebnis der Untersuchungen weist auf eine sehr unbedeutende Änderung des Molekulargewichts des Materials während der Alterung hin.Das Materialgranulat wurde als Bezugsstandard gewählt. Basierend auf der Uneinheitlichkeit D = Mw/Mn des Granulats wurden Filamente der Handelsprodukte GYE 47 und PXC 31399 charakterisiert, deren Alterungsdauer zwischen 2 Wochen und 8 Monaten lag. Bei den Filamenten der Qpe GYE 47 verringerte sich die Breite der Molekulargewichtsverteilung D um durchschnittlich 12%. Andererseits zeigen die Filamente des PXC 31399-vps einen weniger eindeutigen Trend zur Änderung, jedoch im Mittel hat sich die Breite der Verteilung um etwa 20% erniedrigt. Bei letzterem ist die Verteilung iiber die Alterungsdauer stark gestreut. Der GYE 47-Typ zeigt eine nahezu asymptotische Abnahme. Es wird angenommen, daß die Ungleichartigkeit in der Ändenz der Anderung von D zwischen beiden Proben in ihrer unterschiedlichen thermodynamischen Stabilitat liegen ktinnte; PXC 31399 ist weniger stabil.
    Notes: Experiments on the molecular weight variations of physically, room temperature aged isotactic polypropylene (iPP) filaments were done using the High Temperature Gel Permeation Chromatography (HTGPC). Evidence emanating from the studies indicates a very marginal change in molecular weight of the materials during aging.The granules of the materials were chosen as the reference standard. Based on the polydispersity D = Mw/Mn of the granules, filaments of commercial grades GYE 47 and PXC 31399 were characterized between an aging period ranging from 2 weeks to 8 months. The filaments of the GYE 47 grade have their distributions D lowered on the average by about 12%. On the other hand, those of the PXC 31399 grade have a less definite trend in change, but on the average, D is lowered by about 20%. The distributions of this latter grade are highly scattered over the period of aging. The GYE 47 grade shows a reduction in the distribution of a near asymptotic nature. It is believed that the disparity in the trend of change of D between the two samples could be attributed to their relative thermodynamic stability with the PXC 31399 grade being less stable.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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