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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial and engineering chemistry 25 (1986), S. 277-282 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 261 (1983), S. 846-854 
    ISSN: 1435-1536
    Keywords: Melt flow index ; multicomponent polymeric systems ; altered free volume ; state concept
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A model based on the altered free volume state concept has been proposed here to predict the melt flow index values of multicomponent systems as a function of the amount of the dispersed phase. The predictions of the model have been compared with experimental results reported in the literature on a diverse range of multicomponent polymeric systems. The agreement between the model predictions and the experimentally determined values is good.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Rheologica acta 21 (1982), S. 333-339 
    ISSN: 1435-1528
    Keywords: Rheogram ; master curve ; single viscosity measurement ; softening point ; asphalt
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Abstract Asphalt materials are used in a variety of applications such as road paving, waterproofing, roofing membranes, adhesive binders, rust proofing and water resistant coatings. There are available in a number of grades distinguished in terms of their softening point and flow resistance. The selection of the proper grade of asphalt for a particular application is governed by the desired flow behaviour. A knowledge of the complete flow curve depicting the variation of melt viscosity with shear rate at the relevant temperatures is necessary not only for proper grade selection, but also for specifying processing conditions for aggregate mixing and spraying. The rheological data are also useful in assessing end use performance. The scientific techniques for generating the rheological data involve the use of expensive, sophisticated instruments. Generation of the necessary flow data using these instruments is beyond the financial and technical means of most processors of asphalt materials. The engineering techniques involving the use of inexpensive vacuum viscometers are relatively easy, but provide a single point viscosity measurement at low shear rate. In the present work, a method is proposed for unifying the viscosity versus shear rate a data at various temperatures for a number of asphalt grades. A master curve has been generated that is independent of the grade of asphalt and the temperature of viscosity measurement. The master curve can be used to generate rheograms at desired temperatures for the asphalt grade of interest, knowing its zero-shear viscosity at that temperature.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Rheologica acta 23 (1984), S. 368-377 
    ISSN: 1435-1528
    Keywords: Rheological model ; melt flow index ; unified curve ; polymer melt ; engineering design
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Abstract A method has been proposed earlier by Shenoy et al. to estimate complete flow curves depicting the variation of melt viscosity over industrially relevant range of shear rate and temperature through the use of unified curves characteristic of each generic type of polymer. In the present paper, the unified curves have been fitted through modified forms of already known generalized Newtonian models. The advantage of fitting such rheological models to unified curves lies in the fact that calculations involving entrance length estimates, heat transfer, die design, mold design, etc. are greatly simplified. Knowing the model parameters, one needs to know only the melt flow index, which is a relatively easy parameter to obtain, to make any engineering design calculations. The modified generalized Newtonian models have been fitted to a number of polymers covering one or more from each group of olefinics, styrenics, cellulosics, vinyls and engineering thermoplastics.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Rheologica acta 22 (1983), S. 209-222 
    ISSN: 1435-1528
    Keywords: Rheogram ; engineering thermoplastics ; melt flow index
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Abstract A method proposed earlier has been extended to estimate complete flow curves or rheograms of engineering plastics. Master curves that are independent of the grade and temperature have been generated and presented for acrylics, polyacetal, nylons, polyethylene terephthalate, polycarbonate and polysulfone. The influence of the various molecular parameters on the viscosity behaviour of polymer melts have been explained rationally. More specifically, the effects of chain branching and of chain rigidity on the master curve of a resin type have been elucidated with reference to polyacetal and polysulfone, respectively. The method presented here can be used effectively by processors of engineering plastics.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Rheologica acta 23 (1984), S. 608-616 
    ISSN: 1435-1528
    Keywords: Melt flow index ; normal-stress difference ; master curve ; polymeric melt
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Abstract An effective method has been proposed to estimate the primary normalstress difference versus shear rate curves at temperatures relevant to the processing conditions only from the knowledge of the melt flow index, the molecular-weight distribution and the glass transition temperature of the polymer. The method involves the use of a unified curve obtained by coalescing the elastic response curves of various grades in terms of the modified normal-stress coefficientψ 1 ⋅ (MFI)2 and a modified shear rate $$(\bar M_z /\bar M_w )^{3.5} (\dot \gamma /MFI)^2 $$ . Unified curves have been reported for low density polyethylene, high density polyethylene, polypropylene and nylon.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 18 (1983), S. 2149-2155 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Addition of metal halides to nylons has been shown to be advantageous in a number of ways. The decrease in melting temperature, increase in glass transition temperature and melt viscosity by such additions have allowed more convenient processing of low molecular weight polymers and thermally unstable polymers. Rheological data depicting the variation of melt viscosity with shear rate at temperatures relevant to processing are necessary in optimizing and trouble-shooting plastics processing operations. In the present paper, a method has been proposed to estimate, complete flow curves or rheograms of nylon—metal halide systems with the use of a master curve knowing the melt flow index and glass transition temperature of the system. The validity of the approach has been verified for the nylon 6—lithium chloride system and shown to hold good for any nylon—metal halide combination.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 21 (1986), S. 3710-3716 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The dynamic mechanical, electrical and magnetic properties of highly filled magnetic polymeric composites containing 75 to 85 wt % barium ferrite in a thermoplastic elastomer matrix styrene-isoprene-styrene (SIS), are reported. The dependence of the properties on the volume fraction of the filler has been investigated. It is shown that the toughness and shore hardness of the composite may be correlated to its dynamic mechanical parameters. The use of coupling agents for surface treatment of ferrites has been shown to improve the magnetic properties of the composite due to better filler dispersion.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 21 (1986), S. 3710-3716 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The dynamic mechanical, electrical and magnetic properties of highly filled magnetic polymeric composites containing 75 to 85 wt % barium ferrite in a thermoplastic elastomer matrix styrene-isoprene-styrene (SIS), are reported. The dependence of the properties on the volume fraction of the filler has been investigated. It is shown that the toughness and shore hardness of the composite may be correlated to its dynamic mechanical parameters. The use of coupling agents for surface treatment of ferrites has been shown to improve the magnetic properties of the composite due to better filler dispersion.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 26 (1991), S. 5950-5956 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The electrical properties, namely d.c. and a.c. conductivity, of polyester elastomer filled with various metallic and ferrite fillers have been investigated as a function of temperature, frequency and filler concentration. The temperature dependence of resistivity exhibited two regions of low and high activation energy (ΔE). The value of ΔE the lower temperature region (I) decreased while in the higher temperature region (II) it increased with the increase of work function of the metal used. Only in the case of ferrite-filled composites could a positive temperature coefficient of resistance be observed. The frequency dependence of conductivity revealed that there is a very large intergranular capacitance which was even more in the case of ferrite-filled samples than in metal-filled ones. The various results have been explained on the basis of Schottky barrier formation and the depletion regions formed near the polymer-metal interface.
    Type of Medium: Electronic Resource
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