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  • 1
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Advanced materials research Vol. 47-50 (June 2008), p. 278-281 
    ISSN: 1662-8985
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In this paper, effort has been undertaken to study the fracture behavior ofthermoplastic/elastomer (PP/SBS) dynamically vulcanized blends by analyzing the EWF testresults. PP/SBS blends were prepared with concentrations of SBS of 15, 30 and 40 wt%. Deeplydouble edged notched tension (DDENT) specimens were cut from injection molded plaques forfracture testing. It should be noted that the incorporation of SBS to PP seems to enhance fracturetoughness, thus the specific essential work (we) increases with elastomer content. The elastomerparticles contribute to the energy dissipation at the fracture surface and in the outer plastic zone inwhich various types of deformation might have been at work. Also, it seems that the fracturetoughness value levels-off from 30 wt% rubber on. In addition, the incorporation of SBS triggers aconsiderable plastic deformation, since the non-essential work ( βwp) increases compared to thevalue of pure PP. Nonetheless, a decrease in βwp is present with increasing amount of rubber. Sothe EWF method revealed that the dynamic vulcanization method can impair fracture resistance toPP/SBS blends
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Macromolecular Chemistry and Physics 199 (1998), S. 2275-2288 
    ISSN: 1022-1352
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: When crystallisable polymers like isotactic poly(propylene) (iPP) or linear low density polyethylene (LLDPE) are finely dispersed in an incompatible matrix like atactic polystyrene (PS) a fractionated crystallisation process will develop if the number of dispersed droplets is greater than the number of active heterogeneities originally present in the bulk polymer. In this work, several PS/iPP and PS/LLDPE blends were prepared in a composition range where PS was always the matrix component and in some cases compatibilizers were used to enhance dispersion. By applying a self-nucleation procedure we were able to corroborate that what causes the fractionated crystallisation is the lack of highly active heterogeneous nuclei (i.e., those normally active at low supercoolings in the bulk polymer) in every droplet. A detailed characterisation of the particle size distribution was carried out by SEM and the validity of using a Poisson distribution to calculate the concentration of heterogeneities present in one blend system was examined. The calculation of the concentration of heterogeneities can qualitatively explain the presence or absence of particular exotherms in the complex DSC cooling behaviour of some compositions of the PS/LLDPE/SEBS blends. However, the effect of the dispersity of the particle size distribution was found to greatly influence the results. When sufficient amount of a compatibilizer is used to obtain the minimum possible particle size the iPP crystallises exclusively at 45°C. The origin of such crystallisation and the possibility that it may be interpreted as arising from homogeneous nucleation is discussed along with analogous data for dispersed LLDPE.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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