ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Cyclisation (formation of derivatives of 2-methylidene-cyclopentanol or cyclohexanone) with inversion of configuration and retention of optical activity is observed during the solvolysis of secondary γ-allenic tosylates.Steric factors rather than electronic ones control the participation of one of the double bonds in the allenic system. Kinetic results and product distribution are discussed.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19740570309
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