ISSN:
1573-4803
Source:
Springer Online Journal Archives 1860-2000
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
Notes:
Abstract Magnesium bis(phosphorodiamidate) hexahydrate, Mg[PO2(NH2)2]2 · 6H2O, was made by the wet process. The phosphorodiamidate was stable below 5° C, but it was converted to phosphoramidate, orthophosphate, and polyphosphates above 30° C in air. When the phosphorodiamidate was heated in air or in dry nitrogen at a higher temperature, it produced phosphoramidate, ortho- and polyphosphates, and polyphosphates with imino groups. The thermal products in air and in dry nitrogen finally gave Mg(PO3)2 associated with the following reaction at a higher temperature than about 700° C Mg[PO2(NH2)2]2·6H2O→Mg(PO3)+4NH3+4H2O and the product in dry nitrogen still contained 3 to 4% nitrogen.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01148773
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