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  • 1
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 72 (1992), S. 3971-3987 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: A self-consistent continuum (fluid) model for a radio-frequency discharge is presented. The model is one dimensional, incorporates an electron energy balance, and is valid for both electropositive and electronegative discharges. A connection of the fluid model with the underlying physics is presented: issues such as the derivation of the fluid equations from moments of the Boltzmann equation, the closure of the set of moments, and the fundamental assumptions behind the fluid equations are discussed. A detailed set of results for an electropositive and an electronegative discharge is presented, and contrasted. The sustaining mechanisms and the electrical characteristics of the two discharges are also discussed. Comparison with experimental data of spatially and temporally resolved plasma induced emission is successfully done.
    Materialart: Digitale Medien
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  • 2
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 72 (1992), S. 3988-4002 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: A plasma simulator which employs efficient numerical methods is used to do parametric studies on an electropositive (Ar), and an electronegative (SF6) discharge. The effects of pressure and current amplitude variation are studied; the phenomena associated with the transition of the discharge into different operating regimes at low currents, and at high currents, are demonstrated and discussed. Comparison of the model results with experimental data is good. The effect of ion mobility variation with electric field is also studied, and is shown to be important in improving the comparison with experimental data. Finally, a sensitivity analysis on the values of the transport and kinetic parameters is done. The sensitivity analysis and the agreement with experimental data demonstrate the validity of the continuum modeling approach, as long as reasonably accurate experimental data for the model parameters are available.
    Materialart: Digitale Medien
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  • 3
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 80 (1996), S. 1304-1311 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: We report measurements of the energies and angular distributions of positive ions in an inductively coupled argon plasma in a Gaseous Electronics Conference Reference Cell. Use of two separate ion detectors allowed measurement of ion energies and fluxes as a function of position as well as ion angular distributions on the discharge centerline. The inductive drive on our system produced high plasma densities (up to 1012/cm3 electron densities) and relatively stable plasma potentials. As a result, ion energy distributions typically consisted of a single feature well separated from zero energy. Mean ion energy was independent of rf power and varied inversely with pressure, decreasing from 29 to 12 eV as pressure increased from 2.4 to 50 mTorr. The half-widths of the ion angular distributions in these experiments varied from 5° to 9°, or equivalently, the transverse temperatures varied from 0.18 to 0.29 eV with the distributions broadening as either pressure or rf power was increased. © 1996 American Institute of Physics.
    Materialart: Digitale Medien
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  • 4
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 89 (2001), S. 915-922 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Ultraviolet absorption spectroscopy has been used to quantitatively measure CF2 transients in 1 Torr capacitively coupled pulsed plasmas. Time resolved concentrations were obtained for both tetrafluoroethylene (TFE) and hexafluoropropylene oxide (HFPO) feed gases. In the TFE plasma, the CF2 production kinetics follow a first order rise to concentrations of ∼1014/cm3. In the plasma afterglow, a net production of CF2 is observed for a few milliseconds before the transient becomes dominated by a second order recombination process. In the HFPO plasma, three distinct regimes are observed in the plasma on time. Two production regimes exist, one presumably due to HFPO dissociation and the second due to an unknown source, beginning about 5 ms into the on time. Finally, the CF2 concentration passes through a maximum and decreases to steady state. The afterglow processes are similar to those observed for TFE. The production observed in the off time is believed to be related to surface processes. © 2001 American Institute of Physics.
    Materialart: Digitale Medien
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  • 5
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Atomic chlorine concentrations in Cl2 and CF3Cl plasmas have been measured using both infrared absorption spectroscopy and optical emission actinometry. These measurements were made over a range of plasma conditions including plasma excitation frequencies of 72 kHz–13.5 MHz, power inputs of 10–100 W, and pressures of 200–800 mTorr. In Cl2 plasmas, the technique of optical emission actinometry misrepresents atomic chlorine concentration changes by nearly an order of magnitude. The errors in the actinometry technique are believed to result from excited state Cl production by electron impact dissociation of Cl2. A simple model for Cl emission is in good agreement with the experimental observations. In CF3Cl discharges, the technique of optical emission actinometry is shown to accurately represent variations in atomic chlorine concentration with changing process conditions.
    Materialart: Digitale Medien
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  • 6
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 59 (1986), S. 1890-1903 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The measurement and interpretation of ion bombardment energies in rf discharges of SF6, CF3Cl, and CF3Br from 0.2 to 1.0 Torr, are discussed. Errors in ion sampling due to disturbances of the electric field and neutral density around the sampling orifice are shown to be most important at higher pressures and with larger orifices. The dependence of the ion bombardment energy distribution on the electric-field-to-pressure ratio is reviewed. Combining this relation with a simple electrical model of a plasma gives estimates of the ion bombardment energies in collisional sheaths. The bombardment energy is proportional to (rf current)/(electrode area×frequency ×pressure) with the proportionality constant for a particular system depending on the collision cross sections and relative ion-to-netural mass ratio. The constants found for the three gases studied experimentally are close to theoretical estimates.
    Materialart: Digitale Medien
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  • 7
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 62 (1987), S. 799-807 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Atomic chlorine concentrations in Cl2 plasmas have been measured using the technique of infrared absorption spectroscopy. A wide range of plasma conditions were examined, including power input densities of 0.05–0.5 W/cm−3, pressures of 200–800 mTorr, and excitation frequencies of 0.1–13.5 MHz. A simple kinetic model accurately predicts atomic chlorine concentrations as a function of discharge parameters. The primary source of atomic chlorine was assumed to be an electron-impact dissociation of Cl2, and the reaction rate coefficient was assumed to be independent of plasma conditions. The electron density was estimated from a plasma impedance analysis. The depletion of atomic chlorine was successfully modeled assuming second-order recombination on the electrode surfaces; depletion by gas-gas recombination and by flow from the reactor were insignificant over the range of plasma conditions studied. Because the diffusion of atomic chlorine is fast relative to the formation and depletion rates, the atomic chlorine concentration is fairly independent of interelectrode position. Atomic chlorine concentrations were accurately represented by the equation [Cl]=3.5×108 [e−]0.5P0.5, where [Cl] and [e−] are in cm−3 and P is in mTorr.
    Materialart: Digitale Medien
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  • 8
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 63 (1988), S. 2241-2251 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The transport of ions through rf glow-discharge sheaths was simulated with a Monte Carlo method to determine the distributions of ion-bombardment energy and angle of impact. Several sheath parameters were varied and their effects examined: (1) the type of ion-molecule scattering (hard sphere, potential field interaction, charge exchange), (2) the ratio of ion and neutral masses, (3) the ratio of the sheath width to collision mean free path, (4) spatially uniform, spatially linear, and time-dependent (rf) electric fields in the sheath, and (5) the frequency of an rf component in the sheath. The results of the Monte Carlo simulations indicate that the type of elastic scattering (hard sphere or soft sphere) does not significantly change either the impact angle distributions or the scaled ion-bombardment energy distributions. Charge-exchange scattering produces a much greater ion-bombardment directionality and a different shape of the ion-bombardment energy distribution. The fully developed distributions depend only on the ion-to-neutral mass ratio, type of ion-neutral scattering, and the dc value of the electric field-to-pressure ratio at the electrode. Fully developed distributions are reached in approximately three mean free paths in spatially uniform sheath fields and in about six mean free paths for spatially linear sheath fields. The minimum ion directionality was observed when the ion-to-molecule mass ratio was approximately unity. Time-dependent (rf) variation of the sheath field produces features in the ion energy distributions which are similar for both the collisional and collisionless sheaths.
    Materialart: Digitale Medien
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  • 9
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 60 (1986), S. 89-94 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Measured breakdown characteristics of SF6 at 4–14 MHz are compared with the breakdown predicted with an electron-balance model. This balance includes terms for the formation of electrons from ionization of neutral molecules and electron losses by attachment to neutral molecules, electric-field-driven fluxes, and diffusion. With model parameters obtained from existing literature on electron properties in dc electric fields, the model predicts radio frequency (rf) breakdown voltages in agreement with the experimental values. The electron balance model is also expressed in a nondimensional form to aid in generalizing rf breakdown to other gases. The electron concentration profiles formed when including the electric-field-driven fluxes are compared with the sinusoidal distribution achieved for diffusion-controlled breakdown. The success of this model suggests that glow discharges can be modeled in a similar fashion.
    Materialart: Digitale Medien
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