ISSN:
1434-1948
Keywords:
Hydrostannylation
;
Phosphaalkynes
;
1,2-Dihydro-1,3-diphosphetes
;
Homocubanes
;
Carbonyl complexes
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The hydrostannylation of phosphaalkynes 8 with tin hydrides 1 depends on the stoichiometry employed: Thus, the 1,2-dihydro-1,3-diphosphetes 10 are isolated when an excess of phosphaalkyne 8 is used. On the other hand, an increase in the tin hydride concentration favors the formation of the phosphanes 11 and 12. Synthesis of the 1,2-dihydro-1,3-diphosphetes 14 and 16 was achieved by the use of diorganotin hydrides 13 or chloro(organo)tin hydrides 4, respectively. An isolated and characterized by-product of the latter reaction was the phosphorus-carbon-tin cage 17. Furthermore, the following reactions of the 1,2-dihydro-1,3-diphosphetes 10 were performed: isomerization reactions, complexation reactions with transition-metal complexes, and substitution of the hydrogen atom by iodine.
Type of Medium:
Electronic Resource
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