ISSN:
1432-0630
Keywords:
74.70.Vy
;
76.80.+y
Source:
Springer Online Journal Archives 1860-2000
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Abstract The ceramics and single crystals of the Bi2Sr2CaFe2Ox compound were synthesized. The X-ray diffraction data showed orthorhombic symmetry. The lattice parameters are equal toa=5.464 Å,b=5.453 Å,c=31.313 Å. The crystal structure is described by the primitive Bravais lattice with the possible space groups Pbmm. Pbm2 and Pb21m. The obtained X-ray patterns show the presence the incommensurate structural modulation with the following parameters: the modulation vector lies in the (100)-plane, the value of the wave-vector componentq b=0.22(3). The comparison of the obtained results with data for Fe-doped Bi2Sr2CaCu2Ox and Bi2Sr3Fe2Ox are presented. No magnetic peculiarities of the compound were found. Mőssbauer measurements of the ceramic samples indicate the presence mainly of Fe3+ oxidation state and Fe4+ (about 20%). The decrease of the quadrupole-splitting values for 2212Fe in comparison with Fe-doped 2212Cu was revealed that may be connected with higher symmetry of the local environment of Fe atoms in 2212Fe.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01577616
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